The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.
3798-3800
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc
2008
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc
Elsegood, Mark R.J., Kelly, Paul F., Reid, Gillian and Staniland, Paul M.
(2008)
The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4].
Dalton Transactions, 29, .
(doi:10.1039/b806066e).
Abstract
Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.
This record has no associated files available for download.
More information
Published date: 2008
Identifiers
Local EPrints ID: 146989
URI: http://eprints.soton.ac.uk/id/eprint/146989
ISSN: 0300-9246
PURE UUID: 99280192-0a3b-424f-9862-0dfe290f11d7
Catalogue record
Date deposited: 23 Apr 2010 08:17
Last modified: 14 Mar 2024 02:36
Export record
Altmetrics
Contributors
Author:
Mark R.J. Elsegood
Author:
Paul F. Kelly
Author:
Paul M. Staniland
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics