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The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]

The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.
0300-9246
3798-3800
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc

Elsegood, Mark R.J., Kelly, Paul F., Reid, Gillian and Staniland, Paul M. (2008) The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]. Dalton Transactions, 29, 3798-3800. (doi:10.1039/b806066e).

Record type: Article

Abstract

Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.

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Published date: 2008

Identifiers

Local EPrints ID: 146989
URI: http://eprints.soton.ac.uk/id/eprint/146989
ISSN: 0300-9246
PURE UUID: 99280192-0a3b-424f-9862-0dfe290f11d7
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 23 Apr 2010 08:17
Last modified: 20 Jul 2019 01:21

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