The University of Southampton
×
Filter your search:
University of Southampton Institutional Repository

The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]

The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]
Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.
0300-9246
3798-3800
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc
Elsegood, Mark R.J.
cd443b3b-44f9-461c-8310-a885eb86a44e
Kelly, Paul F.
a3668037-0d7a-465a-b258-a907a04e2563
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Staniland, Paul M.
3238869c-6f12-4b0c-b0ca-3204e28d7fdc

Elsegood, Mark R.J., Kelly, Paul F., Reid, Gillian and Staniland, Paul M. (2008) The first use of the free selenimide Ph2SeNH as a synthon; the synthesis and X-ray crystal structure of [Ph2SeNSePh2][BPh4]. Dalton Transactions, 29, 3798-3800. (doi:10.1039/b806066e).

Record type: Article

Abstract

Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2SeNH and Ph2SeNBr.

This record has no associated files available for download.

More information

Published date: 2008
Learn more about Chemistry research

Identifiers

Local EPrints ID: 146989
URI: http://eprints.soton.ac.uk/id/eprint/146989
DOI: doi:10.1039/b806066e
ISSN: 0300-9246
PURE UUID: 99280192-0a3b-424f-9862-0dfe290f11d7
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 23 Apr 2010 08:17
Last modified: 14 Mar 2024 02:36

Export record

Altmetrics

Contributors

Author: Mark R.J. Elsegood
Author: Paul F. Kelly
Author: Gillian Reid ORCID iD
Author: Paul M. Staniland

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information
Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×