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Comparison of chiral and racemic forms of zinc cyclohexane trans-1,2 dicarboxylate frameworks; a structural, computational and calorimetric study

Comparison of chiral and racemic forms of zinc cyclohexane trans-1,2 dicarboxylate frameworks; a structural, computational and calorimetric study
Comparison of chiral and racemic forms of zinc cyclohexane trans-1,2 dicarboxylate frameworks; a structural, computational and calorimetric study
An integrated study of the organic-inorganic framework material zinc cyclohexane trans-1,2-dicarboxylate involving synthesis, structure elucidation, computer simulation, and calorimetry shows that the chiral R,R form (right in picture) is less stable than its racemic R,R/S,S analogue (left) and adopts a layered structure with a fundamentally different topology. The results point to the possibility that the structural diversity of racemic frameworks and their homochiral analogues may be much greater than has hitherto been suspected.
calorimetry, chirality, crystal engineering, molecular modeling, organic-inorganic hybrid composites
1433-7851
8634-8637
Bailey, Andrew
681e159f-1563-4350-94eb-e6c01321fbed
Lee, Clare
8112b9af-df6d-4894-8d28-ac00debce159
Feller, Russel K.
69db54ed-7c02-4480-9254-57d1c3fb6a2e
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f
Mellot-Draznieks, Caroline
176ba30d-0197-401c-ab52-247e237c435f
Slater, Ben
d9494ea4-0916-47e1-8127-da6eae488c86
Harrison, William T.A.
3beac7fa-0fea-43ee-a84b-e8a62c1a49ab
Simoncic, P.
3450c99d-2893-4cbc-ada6-9916fd85fb99
Navrotsky, A.
3e11aba5-b904-4538-8f60-721a2c5a3abf
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Cheetham, Anthony K.
e99be992-2a61-4a23-984d-e9fd5f145f61
Bailey, Andrew
681e159f-1563-4350-94eb-e6c01321fbed
Lee, Clare
8112b9af-df6d-4894-8d28-ac00debce159
Feller, Russel K.
69db54ed-7c02-4480-9254-57d1c3fb6a2e
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f
Mellot-Draznieks, Caroline
176ba30d-0197-401c-ab52-247e237c435f
Slater, Ben
d9494ea4-0916-47e1-8127-da6eae488c86
Harrison, William T.A.
3beac7fa-0fea-43ee-a84b-e8a62c1a49ab
Simoncic, P.
3450c99d-2893-4cbc-ada6-9916fd85fb99
Navrotsky, A.
3e11aba5-b904-4538-8f60-721a2c5a3abf
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Cheetham, Anthony K.
e99be992-2a61-4a23-984d-e9fd5f145f61

Bailey, Andrew, Lee, Clare, Feller, Russel K., Orton, James B., Mellot-Draznieks, Caroline, Slater, Ben, Harrison, William T.A., Simoncic, P., Navrotsky, A., Grossel, Martin C. and Cheetham, Anthony K. (2008) Comparison of chiral and racemic forms of zinc cyclohexane trans-1,2 dicarboxylate frameworks; a structural, computational and calorimetric study. Angewandte Chemie International Edition, 47 (45), 8634-8637. (doi:10.1002/anie.200802564). (PMID:18833555)

Record type: Article

Abstract

An integrated study of the organic-inorganic framework material zinc cyclohexane trans-1,2-dicarboxylate involving synthesis, structure elucidation, computer simulation, and calorimetry shows that the chiral R,R form (right in picture) is less stable than its racemic R,R/S,S analogue (left) and adopts a layered structure with a fundamentally different topology. The results point to the possibility that the structural diversity of racemic frameworks and their homochiral analogues may be much greater than has hitherto been suspected.

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More information

e-pub ahead of print date: 2 October 2008
Published date: 27 October 2008
Keywords: calorimetry, chirality, crystal engineering, molecular modeling, organic-inorganic hybrid composites

Identifiers

Local EPrints ID: 147837
URI: https://eprints.soton.ac.uk/id/eprint/147837
ISSN: 1433-7851
PURE UUID: 586d9747-76b4-4fcc-8b5a-3471a139e077
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854

Catalogue record

Date deposited: 26 Apr 2010 14:06
Last modified: 20 Jun 2018 00:36

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