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Combining diffuse reflectance infrared spectroscopy (DRIFTS), dispersive EXAFS, and mass spectrometry with high time resolution: Potential, limitations, and application to the study of NO interaction with supported Rh catalysts

Combining diffuse reflectance infrared spectroscopy (DRIFTS), dispersive EXAFS, and mass spectrometry with high time resolution: Potential, limitations, and application to the study of NO interaction with supported Rh catalysts
Combining diffuse reflectance infrared spectroscopy (DRIFTS), dispersive EXAFS, and mass spectrometry with high time resolution: Potential, limitations, and application to the study of NO interaction with supported Rh catalysts
We describe a new experiment that combines transmission based structural probes, such as dispersive EXAFS (EDE), with diffuse reflectance infrared spectroscopy (DRIFTS) and mass spectrometry (MS), at high time resolution. The potential and limitations of this experiment are
discussed, and an example of its application to the study of fundamental steps occurring during gas–solid interactions is given; that of oxidation and reduction of alumina supported Rh at 573 K using NO and H2, and the structural-reactive role of linear (Rh(NO+)) Rh-nitrosyl species within these processes.
0920-5861
64-72
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69
Newton, Mark A.
73aab2af-4641-47f3-89ad-3b7d3026164f
Dent, Andrew J.
24c2a218-cb0e-4193-af0b-3ff1dc42b552
Fiddy, Steven G.
f6c255cf-6aa1-4798-85ca-1a2ccdaa1186
Jyoti, Bhrat
9e00e347-0864-48fa-9bb8-f44f98161fd0
Evans, John
05890433-0155-49fe-a65d-38c90ea25c69

Newton, Mark A., Dent, Andrew J., Fiddy, Steven G., Jyoti, Bhrat and Evans, John (2007) Combining diffuse reflectance infrared spectroscopy (DRIFTS), dispersive EXAFS, and mass spectrometry with high time resolution: Potential, limitations, and application to the study of NO interaction with supported Rh catalysts. Catalysis Today, 126 (1-2), 64-72. (doi:10.1016/j.cattod.2006.09.034).

Record type: Article

Abstract

We describe a new experiment that combines transmission based structural probes, such as dispersive EXAFS (EDE), with diffuse reflectance infrared spectroscopy (DRIFTS) and mass spectrometry (MS), at high time resolution. The potential and limitations of this experiment are
discussed, and an example of its application to the study of fundamental steps occurring during gas–solid interactions is given; that of oxidation and reduction of alumina supported Rh at 573 K using NO and H2, and the structural-reactive role of linear (Rh(NO+)) Rh-nitrosyl species within these processes.

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Published date: 15 August 2007
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Identifiers

Local EPrints ID: 147889
URI: http://eprints.soton.ac.uk/id/eprint/147889
DOI: doi:10.1016/j.cattod.2006.09.034
ISSN: 0920-5861
PURE UUID: 9aa2d4ba-2511-48b9-9cb5-47b4e8aa985e
ORCID for John Evans: ORCID iD orcid.org/0000-0003-3290-7785

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Date deposited: 27 Apr 2010 08:22
Last modified: 29 Oct 2024 02:32

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Contributors

Author: Mark A. Newton
Author: Andrew J. Dent
Author: Steven G. Fiddy
Author: Bhrat Jyoti
Author: John Evans ORCID iD

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