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Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions

Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions
Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions
Cluster's last stand: Metal nanoparticles, which are well known for their catalytic properties, contain 103-106 atoms in each particle, giving rise to a continuous band of electronic energy levels. As a result, they are very different electronically from metal nanoclusters composed of aggregates of approximately 3-20 atoms. Such nanoclusters themselves exhibit remarkable catalytic performances in hydrogenation and ammoxidation cascade reactions.
cascade reactions, fine chemicals, heterogeneous catalysis, nanoclusters, synergy
1867-3880
402-406
Thomas, John M.
f6fd043f-bee0-42dc-a2ec-56ab2a0cef12
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Gai, Pratibha L.
c000dc82-e443-4da2-90a9-20cfd03c63f5
Grönbeck, Henrik
5fedf278-fd4e-4328-a139-e2a0b1f9a22a
Hernández-Garrido, Juan C.
24b0b97b-6fb3-4896-8cf2-cee5d33fd729
Thomas, John M.
f6fd043f-bee0-42dc-a2ec-56ab2a0cef12
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Gai, Pratibha L.
c000dc82-e443-4da2-90a9-20cfd03c63f5
Grönbeck, Henrik
5fedf278-fd4e-4328-a139-e2a0b1f9a22a
Hernández-Garrido, Juan C.
24b0b97b-6fb3-4896-8cf2-cee5d33fd729

Thomas, John M., Raja, Robert, Gai, Pratibha L., Grönbeck, Henrik and Hernández-Garrido, Juan C. (2010) Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions. ChemCatChem, 2 (4), 402-406. (doi:10.1002/cctc.200900258).

Record type: Article

Abstract

Cluster's last stand: Metal nanoparticles, which are well known for their catalytic properties, contain 103-106 atoms in each particle, giving rise to a continuous band of electronic energy levels. As a result, they are very different electronically from metal nanoclusters composed of aggregates of approximately 3-20 atoms. Such nanoclusters themselves exhibit remarkable catalytic performances in hydrogenation and ammoxidation cascade reactions.

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More information

Published date: 28 February 2010
Keywords: cascade reactions, fine chemicals, heterogeneous catalysis, nanoclusters, synergy

Identifiers

Local EPrints ID: 148275
URI: http://eprints.soton.ac.uk/id/eprint/148275
ISSN: 1867-3880
PURE UUID: b9e84adf-a10f-4204-8c57-0f2816144932
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 27 Apr 2010 15:22
Last modified: 07 Oct 2020 08:14

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