Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions
Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions
Cluster's last stand: Metal nanoparticles, which are well known for their catalytic properties, contain 103-106 atoms in each particle, giving rise to a continuous band of electronic energy levels. As a result, they are very different electronically from metal nanoclusters composed of aggregates of approximately 3-20 atoms. Such nanoclusters themselves exhibit remarkable catalytic performances in hydrogenation and ammoxidation cascade reactions.
cascade reactions, fine chemicals, heterogeneous catalysis, nanoclusters, synergy
402-406
Thomas, John M.
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Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Gai, Pratibha L.
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Grönbeck, Henrik
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Hernández-Garrido, Juan C.
24b0b97b-6fb3-4896-8cf2-cee5d33fd729
28 February 2010
Thomas, John M.
f6fd043f-bee0-42dc-a2ec-56ab2a0cef12
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Gai, Pratibha L.
c000dc82-e443-4da2-90a9-20cfd03c63f5
Grönbeck, Henrik
5fedf278-fd4e-4328-a139-e2a0b1f9a22a
Hernández-Garrido, Juan C.
24b0b97b-6fb3-4896-8cf2-cee5d33fd729
Thomas, John M., Raja, Robert, Gai, Pratibha L., Grönbeck, Henrik and Hernández-Garrido, Juan C.
(2010)
Exceptionally active single-site nanocluster multifunctional catalysts for cascade reactions.
ChemCatChem, 2 (4), .
(doi:10.1002/cctc.200900258).
Abstract
Cluster's last stand: Metal nanoparticles, which are well known for their catalytic properties, contain 103-106 atoms in each particle, giving rise to a continuous band of electronic energy levels. As a result, they are very different electronically from metal nanoclusters composed of aggregates of approximately 3-20 atoms. Such nanoclusters themselves exhibit remarkable catalytic performances in hydrogenation and ammoxidation cascade reactions.
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More information
Published date: 28 February 2010
Keywords:
cascade reactions, fine chemicals, heterogeneous catalysis, nanoclusters, synergy
Identifiers
Local EPrints ID: 148275
URI: http://eprints.soton.ac.uk/id/eprint/148275
ISSN: 1867-3880
PURE UUID: b9e84adf-a10f-4204-8c57-0f2816144932
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Date deposited: 27 Apr 2010 15:22
Last modified: 14 Mar 2024 02:51
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Contributors
Author:
John M. Thomas
Author:
Pratibha L. Gai
Author:
Henrik Grönbeck
Author:
Juan C. Hernández-Garrido
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