Toward less dependence on platinum group metal catalysts: the merits of utilizing tin
Toward less dependence on platinum group metal catalysts: the merits of utilizing tin
Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these “molecular metallic” entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.
9223-9226
Adams, Richard D.
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Blom, Douglas A.
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Captain, Burjor
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Raja, Robert
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Thomas, John Meurig
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Trufan, Eszter
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2 September 2008
Adams, Richard D.
7d7373ac-58af-43f8-9257-8443825f4f69
Blom, Douglas A.
7574519e-a5f3-4892-b823-58500444c01d
Captain, Burjor
17c6b314-5923-40aa-84ad-368b2f3d0245
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Trufan, Eszter
67fe0902-bf57-4b89-832c-9e71eef2bf3c
Adams, Richard D., Blom, Douglas A., Captain, Burjor, Raja, Robert, Thomas, John Meurig and Trufan, Eszter
(2008)
Toward less dependence on platinum group metal catalysts: the merits of utilizing tin.
Langmuir, 24 (17), .
(doi:10.1021/la801759d).
Abstract
Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these “molecular metallic” entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.
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Published date: 2 September 2008
Organisations:
Chemistry
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Local EPrints ID: 148293
URI: http://eprints.soton.ac.uk/id/eprint/148293
ISSN: 0743-7463
PURE UUID: cec8f0b5-a742-4965-9300-9ad52fc90e1d
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Date deposited: 28 Apr 2010 08:24
Last modified: 14 Mar 2024 02:51
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Contributors
Author:
Richard D. Adams
Author:
Douglas A. Blom
Author:
Burjor Captain
Author:
John Meurig Thomas
Author:
Eszter Trufan
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