The University of Southampton
University of Southampton Institutional Repository

Toward less dependence on platinum group metal catalysts: the merits of utilizing tin

Toward less dependence on platinum group metal catalysts: the merits of utilizing tin
Toward less dependence on platinum group metal catalysts: the merits of utilizing tin
Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these “molecular metallic” entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.
0743-7463
9223-9226
Adams, Richard D.
7d7373ac-58af-43f8-9257-8443825f4f69
Blom, Douglas A.
7574519e-a5f3-4892-b823-58500444c01d
Captain, Burjor
17c6b314-5923-40aa-84ad-368b2f3d0245
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Trufan, Eszter
67fe0902-bf57-4b89-832c-9e71eef2bf3c
Adams, Richard D.
7d7373ac-58af-43f8-9257-8443825f4f69
Blom, Douglas A.
7574519e-a5f3-4892-b823-58500444c01d
Captain, Burjor
17c6b314-5923-40aa-84ad-368b2f3d0245
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Trufan, Eszter
67fe0902-bf57-4b89-832c-9e71eef2bf3c

Adams, Richard D., Blom, Douglas A., Captain, Burjor, Raja, Robert, Thomas, John Meurig and Trufan, Eszter (2008) Toward less dependence on platinum group metal catalysts: the merits of utilizing tin. Langmuir, 24 (17), 9223-9226. (doi:10.1021/la801759d).

Record type: Article

Abstract

Minute stoichiometric bimetallic clusters rich in tin (PtSn2, RhSn2, and RuSn2) are powerful selective hydrogenation catalysts: these “molecular metallic” entities, supported on mesoporous silica and characterized by aberration-corrected electron microscopy, yield high percentages of cyclododecene (CDE) at fractional conversions ranging from 0.45 to 0.70 of the parent cyclododecatriene (CDT) at modest temperatures and under solvent-free conditions.

Full text not available from this repository.

More information

Published date: 2 September 2008
Organisations: Chemistry

Identifiers

Local EPrints ID: 148293
URI: https://eprints.soton.ac.uk/id/eprint/148293
ISSN: 0743-7463
PURE UUID: cec8f0b5-a742-4965-9300-9ad52fc90e1d
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 28 Apr 2010 08:24
Last modified: 06 Jun 2018 12:40

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of https://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×