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Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts

Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts
Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts
A solid source of active oxygen (acetylperoxyborate, APB), when dissolved in aqueous solution in the presence of a single-site microporous catalyst containing redox centres (FeIIIAlPO-31, MnIIIAlPO-5, FeIIIAlPO-5), converts cyclohexane with high efficiency (ca. 88%) and exceptionally high selectivity (ca. 81%) to adipic acid at 383 K; this procedure is also effective in converting styrene to styrene oxide and -pinene and (+)-limonene to their corresponding epoxides
1359-7345
448-450
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Xu, Mingcan
61c22b01-700b-4bed-9a26-a74b2e5caf6b
Harris, Kenneth D. M.
1d424af2-3d6d-47d1-b554-51bb10b017ef
Greenhill-Hooper, Michael
f17a45fd-cb9a-4a81-bc65-5e4816e510a5
Quill, Kieran
71750cb1-bfaa-42f0-a7e8-17ff76675392
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Xu, Mingcan
61c22b01-700b-4bed-9a26-a74b2e5caf6b
Harris, Kenneth D. M.
1d424af2-3d6d-47d1-b554-51bb10b017ef
Greenhill-Hooper, Michael
f17a45fd-cb9a-4a81-bc65-5e4816e510a5
Quill, Kieran
71750cb1-bfaa-42f0-a7e8-17ff76675392

Raja, Robert, Thomas, John Meurig, Xu, Mingcan, Harris, Kenneth D. M., Greenhill-Hooper, Michael and Quill, Kieran (2006) Highly efficient one-step conversion of cyclohexane to adipic acid using single-site heterogeneous catalysts. Chemical Communications, 4, 448-450. (doi:10.1039/b513583d).

Record type: Article

Abstract

A solid source of active oxygen (acetylperoxyborate, APB), when dissolved in aqueous solution in the presence of a single-site microporous catalyst containing redox centres (FeIIIAlPO-31, MnIIIAlPO-5, FeIIIAlPO-5), converts cyclohexane with high efficiency (ca. 88%) and exceptionally high selectivity (ca. 81%) to adipic acid at 383 K; this procedure is also effective in converting styrene to styrene oxide and -pinene and (+)-limonene to their corresponding epoxides

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Published date: 2006

Identifiers

Local EPrints ID: 148303
URI: http://eprints.soton.ac.uk/id/eprint/148303
ISSN: 1359-7345
PURE UUID: 9c1a12de-12b8-4cf4-b761-75fd1c1db0f4
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

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Date deposited: 21 Jun 2010 14:15
Last modified: 17 Dec 2019 01:45

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Contributors

Author: Robert Raja ORCID iD
Author: John Meurig Thomas
Author: Mingcan Xu
Author: Kenneth D. M. Harris
Author: Michael Greenhill-Hooper
Author: Kieran Quill

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