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Anion binding properties of 5,5’-dicarboxamido-dipyrrolylmethanes

Anion binding properties of 5,5’-dicarboxamido-dipyrrolylmethanes
Anion binding properties of 5,5’-dicarboxamido-dipyrrolylmethanes
A series of a 5,5’-dicarboxamidodipyrrolylmethanes have been synthesized and in some cases crystallographically characterized. Proton NMR titrations have revealed that these compounds, that contain only four neutral hydrogen bond donors and are acyclic, selectively bind anions in very competitive solvent media such as DMSO-d6/water mixtures.
dipyrrolylmethanes, phosphate, anion binding, supramolecular chemistry
1477-0520
2935-2941
Vega, Ismael El Drubi
b9c8751d-ad70-4a6a-b324-394a3747c206
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Vega, Ismael El Drubi
b9c8751d-ad70-4a6a-b324-394a3747c206
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161

Vega, Ismael El Drubi, Gale, Philip A., Hursthouse, Michael B. and Light, Mark E. (2004) Anion binding properties of 5,5’-dicarboxamido-dipyrrolylmethanes. Organic & Biomolecular Chemistry, 2 (20), 2935-2941. (doi:10.1039/b409115a). (Submitted)

Record type: Article

Abstract

A series of a 5,5’-dicarboxamidodipyrrolylmethanes have been synthesized and in some cases crystallographically characterized. Proton NMR titrations have revealed that these compounds, that contain only four neutral hydrogen bond donors and are acyclic, selectively bind anions in very competitive solvent media such as DMSO-d6/water mixtures.

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Submitted date: 15 June 2004
Keywords: dipyrrolylmethanes, phosphate, anion binding, supramolecular chemistry
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Identifiers

Local EPrints ID: 15718
URI: http://eprints.soton.ac.uk/id/eprint/15718
DOI: doi:10.1039/b409115a
ISSN: 1477-0520
PURE UUID: 31acc8a5-d0c2-4af7-b48a-f8ab842634bb
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 24 May 2005
Last modified: 16 Mar 2024 03:15

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Contributors

Author: Ismael El Drubi Vega
Author: Philip A. Gale ORCID iD
Author: Michael B. Hursthouse
Author: Mark E. Light ORCID iD

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