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Hydrogen bonding networks and anion coordination in (?6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors

Hydrogen bonding networks and anion coordination in (?6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors
Hydrogen bonding networks and anion coordination in (?6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors
A chloride selective amide cleft molecule 2 containing two Cr(CO)?moieties has been synthesised by condensation of (?6-aniline)Cr(CO)?3 with isophthaloyl dichloride; the X-ray crystal structure of 2 contains a network of Cr-CO···HN hydrogen bonds giving rise to an extended three-dimensional coordination array; the X-ray crystal structure of (?6-aniline)Cr(CO)?3 has been re-determined and found to contain bifurcated amine NH···OC-Cr hydrogen bonds.
anion receptor, organometallic, hydrogen bond
1359-7345
275-276
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Mayer, Thomas A.
59bc92dc-0703-4f38-b37d-6e04295371a1
Paver, Michael A.
e140c7ae-e652-49be-a182-10161dcee9fe
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Mayer, Thomas A.
59bc92dc-0703-4f38-b37d-6e04295371a1
Paver, Michael A.
e140c7ae-e652-49be-a182-10161dcee9fe

Camiolo, Salvatore, Coles, Simon J., Gale, Philip A., Hursthouse, Michael B., Mayer, Thomas A. and Paver, Michael A. (2000) Hydrogen bonding networks and anion coordination in (?6-arene)Cr(CO)3 complexes: metal carbonyls as hydrogen bond acceptors. Chemical Communications, (4), 275-276. (doi:10.1039/a909861e).

Record type: Article

Abstract

A chloride selective amide cleft molecule 2 containing two Cr(CO)?moieties has been synthesised by condensation of (?6-aniline)Cr(CO)?3 with isophthaloyl dichloride; the X-ray crystal structure of 2 contains a network of Cr-CO···HN hydrogen bonds giving rise to an extended three-dimensional coordination array; the X-ray crystal structure of (?6-aniline)Cr(CO)?3 has been re-determined and found to contain bifurcated amine NH···OC-Cr hydrogen bonds.

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Submitted date: 15 December 1999
Published date: 2000
Keywords: anion receptor, organometallic, hydrogen bond

Identifiers

Local EPrints ID: 15733
URI: http://eprints.soton.ac.uk/id/eprint/15733
ISSN: 1359-7345
PURE UUID: 7d01aa77-83b8-4e30-8182-396870782509
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 24 May 2005
Last modified: 10 Dec 2019 01:50

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