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Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole clefts

Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole clefts
Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole clefts
Two amido-pyrrole cleft anion receptors bearing two ferrocene reporter groups have been synthesised and crystallographically characterised; the receptors contain either a non-conjugated or conjugated link between the anion-binding amido-pyrrole unit and the ferrocene reporter groups.
The anion binding a?nities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.
ferrocene, anion binding, cyclic voltammetry, microelectrode
1144-0546
811-813
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Warriner, Colin N.
2cdda67a-3408-4a5e-963c-8b0ee7555980

Denuault, Guy, Gale, Philip A., Hursthouse, Michael B., Light, Mark E. and Warriner, Colin N. (2002) Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole clefts. New Journal of Chemistry, 26, 811-813. (doi:10.1039/b202989h).

Record type: Article

Abstract

Two amido-pyrrole cleft anion receptors bearing two ferrocene reporter groups have been synthesised and crystallographically characterised; the receptors contain either a non-conjugated or conjugated link between the anion-binding amido-pyrrole unit and the ferrocene reporter groups.
The anion binding a?nities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively.

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Published date: 2002
Keywords: ferrocene, anion binding, cyclic voltammetry, microelectrode

Identifiers

Local EPrints ID: 15736
URI: http://eprints.soton.ac.uk/id/eprint/15736
ISSN: 1144-0546
PURE UUID: caa0ac8b-638f-48c8-86ab-6b53509c9c7b
ORCID for Guy Denuault: ORCID iD orcid.org/0000-0002-8630-9492
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 24 May 2005
Last modified: 18 Feb 2021 16:55

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Contributors

Author: Guy Denuault ORCID iD
Author: Philip A. Gale ORCID iD
Author: Mark E. Light ORCID iD
Author: Colin N. Warriner

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