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The first example of an anion–pyrrole complex

The first example of an anion–pyrrole complex
The first example of an anion–pyrrole complex
Tetramethylammonium chloride 1 has been recrystallized from pyrrole 2 yielding a pyrrole-chloride complex that has been crystallographically characterized. Complex I contains a chloride anion that is bound by hydrogen bonds from two pyrrole rings and a tetramethylammonium cation. The supramolecular structure is reminiscent of a honeycomb array, comprised of a pyrrole - chloride framework with cavities occupied by tetramethylammonium moities.
crystal engineering, pyrrole, hydrogen bond
1466-8033
1-3
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Coles, Simon J., Gale, Philip A. and Hursthouse, Michael B. (2001) The first example of an anion–pyrrole complex. CrystEngComm, 3 (53), 1-3. (doi:10.1039/b109813f).

Record type: Article

Abstract

Tetramethylammonium chloride 1 has been recrystallized from pyrrole 2 yielding a pyrrole-chloride complex that has been crystallographically characterized. Complex I contains a chloride anion that is bound by hydrogen bonds from two pyrrole rings and a tetramethylammonium cation. The supramolecular structure is reminiscent of a honeycomb array, comprised of a pyrrole - chloride framework with cavities occupied by tetramethylammonium moities.

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Published date: 2001
Keywords: crystal engineering, pyrrole, hydrogen bond

Identifiers

Local EPrints ID: 15738
URI: http://eprints.soton.ac.uk/id/eprint/15738
ISSN: 1466-8033
PURE UUID: ddc0e1bf-1211-459c-b665-1b934b0ee58e
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

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Date deposited: 24 May 2005
Last modified: 06 Jun 2018 12:54

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Author: Simon J. Coles ORCID iD
Author: Philip A. Gale ORCID iD

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