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Solid-state and solution studies of bis-carboxylate binding by bis-amidinium calix[4]arenes

Solid-state and solution studies of bis-carboxylate binding by bis-amidinium calix[4]arenes
Solid-state and solution studies of bis-carboxylate binding by bis-amidinium calix[4]arenes
Bis-amidinium calix[4]arene receptors were shown to coordinate bis-carboxylate anions in DMSO solution; the crystal structure of the malonate salt of one of the receptors revealed a number of different amidinium-carboxylate interactions, demonstrating the propensity of these species to form complex hydrogen bonding networks.
crystal engineering, calixarene, amidinium, molecular networks, protic solvents, receptors, anions, complexation, calixarenes, acid
1364-5471
1294-1298
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Ogden, Mark I.
1461a54b-2593-4f78-98f3-69e77c316903
Skelton, Brian W.
66676fba-373c-43ac-9624-0c022ad4887d
White, Allan H.
fae357a6-2f73-4d4d-8458-f434041ff9f3
Camiolo, Salvatore
4ea1c6a7-c0c9-48a0-8998-66a61de7d4d0
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Ogden, Mark I.
1461a54b-2593-4f78-98f3-69e77c316903
Skelton, Brian W.
66676fba-373c-43ac-9624-0c022ad4887d
White, Allan H.
fae357a6-2f73-4d4d-8458-f434041ff9f3

Camiolo, Salvatore, Gale, Philip A., Ogden, Mark I., Skelton, Brian W. and White, Allan H. (2001) Solid-state and solution studies of bis-carboxylate binding by bis-amidinium calix[4]arenes. Journal of the Chemical Society, Perkin Transactions 2, 1294-1298. (doi:10.1039/b102831f).

Record type: Article

Abstract

Bis-amidinium calix[4]arene receptors were shown to coordinate bis-carboxylate anions in DMSO solution; the crystal structure of the malonate salt of one of the receptors revealed a number of different amidinium-carboxylate interactions, demonstrating the propensity of these species to form complex hydrogen bonding networks.

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More information

Published date: 2001
Keywords: crystal engineering, calixarene, amidinium, molecular networks, protic solvents, receptors, anions, complexation, calixarenes, acid

Identifiers

Local EPrints ID: 15742
URI: https://eprints.soton.ac.uk/id/eprint/15742
ISSN: 1364-5471
PURE UUID: 58351937-8f5a-46a0-8caf-1623eb11fbaa
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 24 May 2005
Last modified: 20 Jul 2019 01:07

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