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Electrodeposition of highly ordered macroporous iridium oxide through self-assembled colloidal templates

Electrodeposition of highly ordered macroporous iridium oxide through self-assembled colloidal templates
Electrodeposition of highly ordered macroporous iridium oxide through self-assembled colloidal templates
Iridium oxide electrodeposited through a self-assembled colloidal template has an inverse opal structure. Monolayers present long range hexagonal arrangements of hemispherical nanocavities while multilayers present 3D honeycomb structures with spherical voids. The films are amorphous, have several electroactive redox states and are electrochromic. The nanostructure modifies their reflectivity thus indicating that these films could be used as tunable photonic devices.
3855-3858
Hu, Jin
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Abdelsalam, Mamdouh
d1cbddcb-9f5c-46d5-b774-1bbaee26e115
Bartlett, Philip
d99446db-a59d-4f89-96eb-f64b5d8bb075
Cole, Robin
fa1cb1a2-f042-4650-823c-84f9db2da9ef
Sugawara, Yoshihiro
ff9d9d87-d80a-4158-87c8-06eb84d1cd36
Baumberg, Jeremy
44ce7dca-7035-4043-9a92-3e8a69a31f72
Mahajan, Sumeet
b131f40a-479e-4432-b662-19d60d4069e9
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e
Hu, Jin
e4ccc3ed-b4b1-4be1-8264-66d734ee7186
Abdelsalam, Mamdouh
d1cbddcb-9f5c-46d5-b774-1bbaee26e115
Bartlett, Philip
d99446db-a59d-4f89-96eb-f64b5d8bb075
Cole, Robin
fa1cb1a2-f042-4650-823c-84f9db2da9ef
Sugawara, Yoshihiro
ff9d9d87-d80a-4158-87c8-06eb84d1cd36
Baumberg, Jeremy
44ce7dca-7035-4043-9a92-3e8a69a31f72
Mahajan, Sumeet
b131f40a-479e-4432-b662-19d60d4069e9
Denuault, Guy
5c76e69f-e04e-4be5-83c5-e729887ffd4e

Hu, Jin, Abdelsalam, Mamdouh, Bartlett, Philip, Cole, Robin, Sugawara, Yoshihiro, Baumberg, Jeremy, Mahajan, Sumeet and Denuault, Guy (2009) Electrodeposition of highly ordered macroporous iridium oxide through self-assembled colloidal templates. Journal of Materials Chemistry, 19 (23), 3855-3858. (doi:10.1039/b900279k).

Record type: Article

Abstract

Iridium oxide electrodeposited through a self-assembled colloidal template has an inverse opal structure. Monolayers present long range hexagonal arrangements of hemispherical nanocavities while multilayers present 3D honeycomb structures with spherical voids. The films are amorphous, have several electroactive redox states and are electrochromic. The nanostructure modifies their reflectivity thus indicating that these films could be used as tunable photonic devices.

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More information

e-pub ahead of print date: 24 April 2009
Published date: 2009
Organisations: Chemistry

Identifiers

Local EPrints ID: 158677
URI: http://eprints.soton.ac.uk/id/eprint/158677
PURE UUID: 8032df43-8901-4bd2-89ea-37851d2f8418
ORCID for Philip Bartlett: ORCID iD orcid.org/0000-0002-7300-6900
ORCID for Sumeet Mahajan: ORCID iD orcid.org/0000-0001-8923-6666
ORCID for Guy Denuault: ORCID iD orcid.org/0000-0002-8630-9492

Catalogue record

Date deposited: 24 Jun 2010 08:20
Last modified: 14 Mar 2024 02:52

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Contributors

Author: Jin Hu
Author: Mamdouh Abdelsalam
Author: Philip Bartlett ORCID iD
Author: Robin Cole
Author: Yoshihiro Sugawara
Author: Jeremy Baumberg
Author: Sumeet Mahajan ORCID iD
Author: Guy Denuault ORCID iD

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