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Investigation of transport across an immiscible liquid/liquid interface - Electrochemical and second harmonic generation studies

Crawford, M.J., Frey, J.G., VanderNoot, T.J. and Zhao, Y.G. (1996) Investigation of transport across an immiscible liquid/liquid interface - Electrochemical and second harmonic generation studies Journal of the Chemical Society - Faraday Transactions, 92, (8), pp. 1369-1373. (doi:10.1039/FT9969201369).

Record type: Article

Abstract

An electrochemical investigation of the transport of the crown ether 4'-nitrobenzo-15-crown-5 across a water/1,2- dichloroethane interface showed that the crown ether did not cross the interface but the complex formed by the crown ether with Na+ did transfer, the peak transfer current increased with increasing [Na+] until all the crown ether was complexed. The in situ interfacial second harmonic generation experiment indicates that, in the absence of Na+, the crown ether is oriented and ordered by the electric field at the interface. The sodium coronate shows a more complex behaviour at the interface.

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Published date: 1996

Identifiers

Local EPrints ID: 15921
URI: http://eprints.soton.ac.uk/id/eprint/15921
PURE UUID: 65bad7a7-0354-4171-94d5-b04e11364e6d

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Date deposited: 14 Jun 2005
Last modified: 17 Jul 2017 16:44

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Contributors

Author: M.J. Crawford
Author: J.G. Frey
Author: T.J. VanderNoot
Author: Y.G. Zhao

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