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Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states

Bell, A.J., Boggis, S.A., Dyke, J.M., Frey, J.G., Richter, R., Shaw, N. and Tabrizchi, M. (1994) Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states Journal of the Chemical Society, Faraday Transactions, 90, (1), pp. 17-21. (doi:10.1039/FT9949000017).

Record type: Article

Abstract

The nascent chlorine atom (P-2) relative spin-orbit state population resulting from UV photolysis of HOCl has been measured by resonance-enhanced multiphoton ionization (REMPI) in single laser experiments. The ratio of (0.30 +/- 0.07) for Cl*:Cl has been obtained, indicating a stronger preference for production of ground-state Cl(P-2(3/2)) than expected from statistical weights. Also, the Cl+ arrival-time spectra show that most of the energy available in the photolysis is converted into kinetic energy of the photofragments.

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Published date: 1994

Identifiers

Local EPrints ID: 15925
URI: http://eprints.soton.ac.uk/id/eprint/15925
PURE UUID: a6fd4a5a-e1d9-4ab1-ba81-f74348f0d3ca
ORCID for J.M. Dyke: ORCID iD orcid.org/0000-0002-9808-303X
ORCID for J.G. Frey: ORCID iD orcid.org/0000-0003-0842-4302

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Date deposited: 14 Jun 2005
Last modified: 17 Jul 2017 16:44

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Contributors

Author: A.J. Bell
Author: S.A. Boggis
Author: J.M. Dyke ORCID iD
Author: J.G. Frey ORCID iD
Author: R. Richter
Author: N. Shaw
Author: M. Tabrizchi

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