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Second harmonic generation by p-nitrophenol at water/air and water/heptane interfaces

Bell, A.J., Frey, J.G. and Vandernoot, T.J. (1992) Second harmonic generation by p-nitrophenol at water/air and water/heptane interfaces Journal of the Chemical Society - Faraday Transactions, 88, (14), pp. 2027-2030. (doi:10.1039/FT9928802027).

Record type: Article

Abstract

Interfacial second harmonic generation by p-nitrophenol at air/water and heptane/water interfaces has been investigated. The preliminary results indicate that the orientation of the p- nitrophenol is slightly different in the two cases. but the influence of the resonant enhancement on the two important components of the molecular hyperpolarisability (beta(zzz) and beta(zxx)) differs significantly in the two systems. The difference is attributed to the change in the absorption spectrum of p-nitrophenol in heptane and water.

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Published date: 1992

Identifiers

Local EPrints ID: 15930
URI: http://eprints.soton.ac.uk/id/eprint/15930
PURE UUID: ad408569-71d0-468a-8bb8-53dc51b80b79

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Date deposited: 17 Jun 2005
Last modified: 17 Jul 2017 16:44

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Author: A.J. Bell
Author: J.G. Frey
Author: T.J. Vandernoot

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