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The 248 nm photodissociation of DOCl: laser excitation fluorescence spectra of OD

Hickman, C.G., Brickell, A. and Frey, J.G. (1991) The 248 nm photodissociation of DOCl: laser excitation fluorescence spectra of OD Chemical Physics Letters, 185, (1-2), pp. 101-104. (doi:10.1016/0009-2614(91)80147-P).

Record type: Article

Abstract

The dynamics of the 248 nm excimer-laser-induced photodissociation of DOCl has been investigated by the observation of the OD fragment by laser excitation fluorescence. The OD PI(A') lambda doublet state is strongly favoured in the dissociation and there is a small preference for the 2-PI-3/2 spin-orbit state. The observed OD rotational distribution differs for the two lambda doublets, and for the PI(A') component of the 2-PI-3/2 spin-orbit state the distribution is Gaussian. The results are interpreted in terms of a fast dissociation with most of the energy released into relative translational energy. The rotational distribution can be explained with a Franck-Condon type model.

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Published date: 1991

Identifiers

Local EPrints ID: 15934
URI: http://eprints.soton.ac.uk/id/eprint/15934
ISSN: 0009-2614
PURE UUID: 488df9f4-6c23-45ed-8565-9da930458276

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Date deposited: 20 Jun 2005
Last modified: 17 Jul 2017 16:44

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Contributors

Author: C.G. Hickman
Author: A. Brickell
Author: J.G. Frey

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