Calix[n]pyrroles as anion and ion-pair complexants
Calix[n]pyrroles as anion and ion-pair complexants
This chapter covers advances in calixpyrrole chemistry and specifically in the application of these species as anion and ion-pair complexation agents over the last 5 years. Over this time, the chemistry of these easy-to-make macrocycles advanced with the discovery of the ion-pair complexation properties of calixpyrroles, in addition to the development of strapped calixpyrroles that incorporate extra hydrogen bond donors and possess higher affinities for anions than the parent macrocycle. Calixpyrroles have also been employed as anion complexants in solvent–solvent extraction and in polymers. They have also been shown to function as lipid bilayer transport agents for salts and as organocatalysts.
39-73
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lee, Chang-Hee
af3c694a-0258-4db9-ab36-83ab603097f7
2010
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Lee, Chang-Hee
af3c694a-0258-4db9-ab36-83ab603097f7
Gale, Philip A. and Lee, Chang-Hee
(2010)
Calix[n]pyrroles as anion and ion-pair complexants.
Topics in Heterocyclic Chemistry, 25, .
(doi:10.1007/7081_2010_30).
Abstract
This chapter covers advances in calixpyrrole chemistry and specifically in the application of these species as anion and ion-pair complexation agents over the last 5 years. Over this time, the chemistry of these easy-to-make macrocycles advanced with the discovery of the ion-pair complexation properties of calixpyrroles, in addition to the development of strapped calixpyrroles that incorporate extra hydrogen bond donors and possess higher affinities for anions than the parent macrocycle. Calixpyrroles have also been employed as anion complexants in solvent–solvent extraction and in polymers. They have also been shown to function as lipid bilayer transport agents for salts and as organocatalysts.
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Published date: 2010
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Local EPrints ID: 170327
URI: http://eprints.soton.ac.uk/id/eprint/170327
ISSN: 1861-9282
PURE UUID: 38234e62-303d-4ef4-89c8-277ed309f8bc
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Date deposited: 05 Jan 2011 14:47
Last modified: 14 Mar 2024 02:44
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Author:
Philip A. Gale
Author:
Chang-Hee Lee
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