Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations
Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations
The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.
517-519
Paterson, James
bf6ad53e-007e-41c9-8ef0-551a7a0d53ce
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
2011
Paterson, James
bf6ad53e-007e-41c9-8ef0-551a7a0d53ce
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Paterson, James, Potter, Matthew, Gianotti, Enrica and Raja, Robert
(2011)
Engineering active sites for enhancing synergy in heterogeneous catalytic oxidations.
Chemical Communications, 47 (1), .
(doi:10.1039/c0cc02341h).
(PMID:21038071)
Abstract
The simultaneous isomorphous substitution of Al(III) and P(V) ions, in an aluminophosphate framework, with redox active Co(III) and Ti(IV) metal ions, generates highly active single-site heterogeneous catalysts that exhibit considerable synergy, compared to their corresponding monometallic analogues, in the catalytic epoxidation of olefins.
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Published date: 2011
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Local EPrints ID: 176821
URI: http://eprints.soton.ac.uk/id/eprint/176821
ISSN: 1359-7345
PURE UUID: a3ceb272-4934-461a-bae8-ad24139e13f5
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Date deposited: 11 Mar 2011 14:22
Last modified: 14 Mar 2024 02:51
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Author:
James Paterson
Author:
Enrica Gianotti
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