The University of Southampton
University of Southampton Institutional Repository

Thieme chemistry journal awardees - Where are they now? Stabilisation of porphyrins in tetranucleotide-bisporphyrin arrays by duplex formation with peptide nucleic acid

Thieme chemistry journal awardees - Where are they now? Stabilisation of porphyrins in tetranucleotide-bisporphyrin arrays by duplex formation with peptide nucleic acid
Thieme chemistry journal awardees - Where are they now? Stabilisation of porphyrins in tetranucleotide-bisporphyrin arrays by duplex formation with peptide nucleic acid
UV irradiation of porphyrins in tetranucleotide-bisporphyrin arrays in organic solvents leads to selective bleaching of diphenyl porphyrins but not of tetraphenyl porphyrins. This was shown by absorbance and CD spectroscopy. The diphenyl porphyrin can be stabilised by duplex formation with a complementary PNA strand. These arrays are versatile building blocks for the synthesis of potential electronic arrays using a DNA scaffolding approach.

porphyrins, nucleotides, spectroscopy, supramolecular array
0936-5214
2913-2918
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Bouamaied, Imenne
9938a8f5-740f-4c9c-9285-8a16a43a5fe5
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Bouamaied, Imenne
9938a8f5-740f-4c9c-9285-8a16a43a5fe5

Stulz, Eugen and Bouamaied, Imenne (2009) Thieme chemistry journal awardees - Where are they now? Stabilisation of porphyrins in tetranucleotide-bisporphyrin arrays by duplex formation with peptide nucleic acid. Synlett, 18, 2913-2918. (doi:10.1055/s-0029-1218277).

Record type: Article

Abstract

UV irradiation of porphyrins in tetranucleotide-bisporphyrin arrays in organic solvents leads to selective bleaching of diphenyl porphyrins but not of tetraphenyl porphyrins. This was shown by absorbance and CD spectroscopy. The diphenyl porphyrin can be stabilised by duplex formation with a complementary PNA strand. These arrays are versatile building blocks for the synthesis of potential electronic arrays using a DNA scaffolding approach.

Full text not available from this repository.

More information

Published date: 2009
Keywords: porphyrins, nucleotides, spectroscopy, supramolecular array

Identifiers

Local EPrints ID: 176847
URI: http://eprints.soton.ac.uk/id/eprint/176847
ISSN: 0936-5214
PURE UUID: 10569db6-8d70-4d75-9b44-e90ccb874069
ORCID for Eugen Stulz: ORCID iD orcid.org/0000-0002-5302-2276

Catalogue record

Date deposited: 11 Mar 2011 12:06
Last modified: 20 Jul 2019 00:54

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×