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Designing a heterogeneous catalyst for the production of adipic acid by aerial oxidation of cyclohexane

Designing a heterogeneous catalyst for the production of adipic acid by aerial oxidation of cyclohexane
Designing a heterogeneous catalyst for the production of adipic acid by aerial oxidation of cyclohexane
A critical dependence upon molecular constraints is found for the aerial, free radical, shape-selective oxidation of cyclohexane. The oxidation occurs at the FeIII sites inside the framework of FeAlPO molecular-sieve catalysts. Oxidation of cyclohexane with the catalyst FeAlPO5 produces predominantly cyclohexanol and cyclohexanone, but with FeAlPO31 adipic acid is produced.

adipic acid, catalysts, heterogeneous catalysis, microporosity, oxidations
1433-7851
2310-2313
Dugal, Markus
0eea5021-4f37-4f3e-b8c1-2d3be74d1266
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Dugal, Markus
0eea5021-4f37-4f3e-b8c1-2d3be74d1266
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd

Dugal, Markus, Sankar, Gopinathan, Raja, Robert and Thomas, John Meurig (2000) Designing a heterogeneous catalyst for the production of adipic acid by aerial oxidation of cyclohexane. Angewandte Chemie International Edition, 39 (13), 2310-2313. (doi:10.1002/1521-3773(20000703)39:13<2310::AID-ANIE2310>3.0.CO;2-G). (PMID:10941074)

Record type: Article

Abstract

A critical dependence upon molecular constraints is found for the aerial, free radical, shape-selective oxidation of cyclohexane. The oxidation occurs at the FeIII sites inside the framework of FeAlPO molecular-sieve catalysts. Oxidation of cyclohexane with the catalyst FeAlPO5 produces predominantly cyclohexanol and cyclohexanone, but with FeAlPO31 adipic acid is produced.

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More information

Published date: 3 July 2000
Keywords: adipic acid, catalysts, heterogeneous catalysis, microporosity, oxidations
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Identifiers

Local EPrints ID: 176877
URI: http://eprints.soton.ac.uk/id/eprint/176877
DOI: doi:10.1002/1521-3773(20000703)39:13<2310::AID-ANIE2310>3.0.CO;2-G
ISSN: 1433-7851
PURE UUID: 1db3a2cb-9b8a-42ce-a12b-c570b8409b94
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 11 Mar 2011 14:47
Last modified: 14 Mar 2024 02:51

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Contributors

Author: Markus Dugal
Author: Gopinathan Sankar
Author: Robert Raja ORCID iD
Author: John Meurig Thomas

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