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A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst

A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst
A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst
A chiral catalyst derived from 1,1?-bis(diphenylphosphino)ferrocene and anchored within MCM-41 displays remarkable increases in both enantioselectivity and activity, in the hydrogenation of ethyl nicotinate to ethyl nipecotinate, when compared to an analogous homogeneous model compound.

1359-7345
1925-1926
Raynor, Stuart A.
11dc2e79-1d9f-4a03-ab7e-bfd6fa58392d
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Johnson, Brian F. G.
d5f4f2a1-c50e-4bd6-82c6-64e4ea238813
Bell, Robert G.
47951797-cf55-4b61-bc7a-25a1da365711
Mantle, Mike D.
adbbb994-369a-4fee-a2cb-ebc37ca30e2a
Raynor, Stuart A.
11dc2e79-1d9f-4a03-ab7e-bfd6fa58392d
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Johnson, Brian F. G.
d5f4f2a1-c50e-4bd6-82c6-64e4ea238813
Bell, Robert G.
47951797-cf55-4b61-bc7a-25a1da365711
Mantle, Mike D.
adbbb994-369a-4fee-a2cb-ebc37ca30e2a

Raynor, Stuart A., Thomas, John Meurig, Raja, Robert, Johnson, Brian F. G., Bell, Robert G. and Mantle, Mike D. (2000) A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst. Chemical Communications, (19), 1925-1926. (doi:10.1039/B005689H).

Record type: Article

Abstract

A chiral catalyst derived from 1,1?-bis(diphenylphosphino)ferrocene and anchored within MCM-41 displays remarkable increases in both enantioselectivity and activity, in the hydrogenation of ethyl nicotinate to ethyl nipecotinate, when compared to an analogous homogeneous model compound.

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Published date: 2000

Identifiers

Local EPrints ID: 176879
URI: http://eprints.soton.ac.uk/id/eprint/176879
ISSN: 1359-7345
PURE UUID: 3c4bbb4e-dca3-4370-ad1e-ed67e852a32f
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

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Date deposited: 14 Mar 2011 11:34
Last modified: 17 Dec 2019 01:45

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