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Designing a molecular sieve catalyst for the aerial oxidation of n-hexane to adipic acid

Designing a molecular sieve catalyst for the aerial oxidation of n-hexane to adipic acid
Designing a molecular sieve catalyst for the aerial oxidation of n-hexane to adipic acid
The aerobic oxyfunctionalization of both (methyl) ends of n-hexane by a MAlPO-18 catalyst requires a significant amount of higher valent framework cobalt ions (M=CoIII) located on the inner walls of each cage of the AlPO-18 structure (Co:P ratio ca. 0.10; see picture). The two tetrahedrally coordinated CoIII framework ions per cage are separated by about 7–8 Å. The CoIII ions function as centers for the regioselective oxidation of both ends of the n-hexane molecule to produce adipic acid.

adipic acid, catalysts, heterogeneous catalysis, n-hexane, oxidations
1433-7851
2313-2316
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd

Raja, Robert, Sankar, Gopinathan and Thomas, John Meurig (2000) Designing a molecular sieve catalyst for the aerial oxidation of n-hexane to adipic acid. Angewandte Chemie International Edition, 39 (13), 2313-2316. (doi:10.1002/1521-3773(20000703)39:13<2313::AID-ANIE2313>3.0.CO;2-Z).

Record type: Article

Abstract

The aerobic oxyfunctionalization of both (methyl) ends of n-hexane by a MAlPO-18 catalyst requires a significant amount of higher valent framework cobalt ions (M=CoIII) located on the inner walls of each cage of the AlPO-18 structure (Co:P ratio ca. 0.10; see picture). The two tetrahedrally coordinated CoIII framework ions per cage are separated by about 7–8 Å. The CoIII ions function as centers for the regioselective oxidation of both ends of the n-hexane molecule to produce adipic acid.

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More information

Published date: 3 July 2000
Keywords: adipic acid, catalysts, heterogeneous catalysis, n-hexane, oxidations
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Identifiers

Local EPrints ID: 176899
URI: http://eprints.soton.ac.uk/id/eprint/176899
DOI: doi:10.1002/1521-3773(20000703)39:13<2313::AID-ANIE2313>3.0.CO;2-Z
ISSN: 1433-7851
PURE UUID: 8ea5a601-6f9b-4a6f-bb00-eb0b5d4c5250
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

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Date deposited: 11 Mar 2011 15:20
Last modified: 17 Dec 2019 01:45

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Author: Robert Raja ORCID iD
Author: Gopinathan Sankar
Author: John Meurig Thomas

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