New catalysts for the aerobic selective oxidation of hydrocarbons: Mn(III)- and Co(III)-containing molecular sieves for the epoxidation of alkenes
New catalysts for the aerobic selective oxidation of hydrocarbons: Mn(III)- and Co(III)-containing molecular sieves for the epoxidation of alkenes
Co(III) or Mn(III) ions that replace some 4 atom% of Al(III) sites in microporous aluminophosphate number 36 (AlPO-36) function as catalytically active centres for the production from benzaldehyde of acylperoxy radicals: these, in turn, in dry air (30 bar) convert cyclohexene, pinene, limonene and styrene to their corresponding epoxides and diols.
829-830
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
1999
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Raja, Robert, Sankar, Gopinathan and Thomas, John Meurig
(1999)
New catalysts for the aerobic selective oxidation of hydrocarbons: Mn(III)- and Co(III)-containing molecular sieves for the epoxidation of alkenes.
Chemical Communications, (9), .
(doi:10.1039/A901127G).
Abstract
Co(III) or Mn(III) ions that replace some 4 atom% of Al(III) sites in microporous aluminophosphate number 36 (AlPO-36) function as catalytically active centres for the production from benzaldehyde of acylperoxy radicals: these, in turn, in dry air (30 bar) convert cyclohexene, pinene, limonene and styrene to their corresponding epoxides and diols.
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Published date: 1999
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Local EPrints ID: 176911
URI: http://eprints.soton.ac.uk/id/eprint/176911
ISSN: 1359-7345
PURE UUID: 02e44029-cb3d-4854-bd1f-7b220aac3f5e
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Date deposited: 11 Mar 2011 15:43
Last modified: 14 Mar 2024 02:51
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Author:
Gopinathan Sankar
Author:
John Meurig Thomas
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