Preparation and characterisation of a highly active bimetallic (Pd–Ru) nanoparticle heterogeneous catalyst
Preparation and characterisation of a highly active bimetallic (Pd–Ru) nanoparticle heterogeneous catalyst
The mixed-metal carbonylate cluster [Pd6Ru6(CO)24]2– was used as a single-source precursor in the synthesis of a highly active hydrogenation catalyst (stoichiometry PdRu) which has been characterised by electron microscopy and X-ray absorption spectroscopy: PdRu readily hydrogenates alkenes and naphthalene (the latter predominantly to cis- decalin) under mild conditions
1571-1572
Raja, Robert
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Hermans, Sophie
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Shephard, Douglas S.
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Johnson, Brian F.G.
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Sankar, Gopinathan
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Bromley, Stefan
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Thomas, John Meurig
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1999
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Hermans, Sophie
8350487f-94e5-4bf2-9c6d-e845d3b9f4f9
Shephard, Douglas S.
029e6969-8e45-4a8a-9d92-424d328caba0
Johnson, Brian F.G.
4912806f-8ff8-4315-aa16-7701bf48a34a
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Bromley, Stefan
f15d6ec7-c1b5-4a3d-b16e-6ed311839f23
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Raja, Robert, Hermans, Sophie, Shephard, Douglas S., Johnson, Brian F.G., Sankar, Gopinathan, Bromley, Stefan and Thomas, John Meurig
(1999)
Preparation and characterisation of a highly active bimetallic (Pd–Ru) nanoparticle heterogeneous catalyst.
Chemical Communications, (16), .
(doi:10.1039/A901263J).
Abstract
The mixed-metal carbonylate cluster [Pd6Ru6(CO)24]2– was used as a single-source precursor in the synthesis of a highly active hydrogenation catalyst (stoichiometry PdRu) which has been characterised by electron microscopy and X-ray absorption spectroscopy: PdRu readily hydrogenates alkenes and naphthalene (the latter predominantly to cis- decalin) under mild conditions
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Published date: 1999
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Local EPrints ID: 176913
URI: http://eprints.soton.ac.uk/id/eprint/176913
ISSN: 1359-7345
PURE UUID: d5bac373-8007-4cdd-9f59-31179a3dd351
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Date deposited: 14 Mar 2011 10:14
Last modified: 14 Mar 2024 02:51
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Contributors
Author:
Sophie Hermans
Author:
Douglas S. Shephard
Author:
Brian F.G. Johnson
Author:
Gopinathan Sankar
Author:
Stefan Bromley
Author:
John Meurig Thomas
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