Preparation, characterisation and performance of encapsulated copper-ruthenium bimetallic catalysts derived from molecular cluster carbonyl precursors
Preparation, characterisation and performance of encapsulated copper-ruthenium bimetallic catalysts derived from molecular cluster carbonyl precursors
High-performance, bimetallic nanoparticle catalysts (M1+M2) were obtained by gentle thermolysis of their precursor metal-cluster carbonylates physisorbed inside the mesoporous channels of silica (the hexagons in the figure). The Cu–Ru catalyst anchored on silica is stable in use and has been tested in the catalytic hydrogenation of hex-1-ene, diphenylacetylene, phenylacetylene, stilbene, cis-cyclooctene, and D-limonene.
bimetallic nanoparticles, clusters, copper, heterogeneous catalysis, hydrogenations, ruthenium
1214-1224
Shephard, Douglas S.
029e6969-8e45-4a8a-9d92-424d328caba0
Maschmeyer, Thomas
1dd6f4e5-295a-4831-965e-05709023f908
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Ozkaya, Dogan
d6b30e54-3986-41af-a129-d20c42ff94d7
Johnson, Brian F.G.
4912806f-8ff8-4315-aa16-7701bf48a34a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Oldroyd, Richard D.
1d47b0d6-5f7a-4bbe-be52-54a74b1b09a5
Bell, Robert G.
47951797-cf55-4b61-bc7a-25a1da365711
10 July 1998
Shephard, Douglas S.
029e6969-8e45-4a8a-9d92-424d328caba0
Maschmeyer, Thomas
1dd6f4e5-295a-4831-965e-05709023f908
Sankar, Gopinathan
31dc72ca-310b-407f-9d6c-856dbfb2e2d1
Thomas, John Meurig
f1d9bb61-4e2c-4c4b-8115-953d0f3d36bd
Ozkaya, Dogan
d6b30e54-3986-41af-a129-d20c42ff94d7
Johnson, Brian F.G.
4912806f-8ff8-4315-aa16-7701bf48a34a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Oldroyd, Richard D.
1d47b0d6-5f7a-4bbe-be52-54a74b1b09a5
Bell, Robert G.
47951797-cf55-4b61-bc7a-25a1da365711
Shephard, Douglas S., Maschmeyer, Thomas, Sankar, Gopinathan, Thomas, John Meurig, Ozkaya, Dogan, Johnson, Brian F.G., Raja, Robert, Oldroyd, Richard D. and Bell, Robert G.
(1998)
Preparation, characterisation and performance of encapsulated copper-ruthenium bimetallic catalysts derived from molecular cluster carbonyl precursors.
Chemistry - A European Journal, 4 (7), .
(doi:10.1002/(SICI)1521-3765(19980710)4:7<1214::AID-CHEM1214>3.0.CO;2-E).
Abstract
High-performance, bimetallic nanoparticle catalysts (M1+M2) were obtained by gentle thermolysis of their precursor metal-cluster carbonylates physisorbed inside the mesoporous channels of silica (the hexagons in the figure). The Cu–Ru catalyst anchored on silica is stable in use and has been tested in the catalytic hydrogenation of hex-1-ene, diphenylacetylene, phenylacetylene, stilbene, cis-cyclooctene, and D-limonene.
This record has no associated files available for download.
More information
Published date: 10 July 1998
Keywords:
bimetallic nanoparticles, clusters, copper, heterogeneous catalysis, hydrogenations, ruthenium
Identifiers
Local EPrints ID: 176927
URI: http://eprints.soton.ac.uk/id/eprint/176927
ISSN: 0947-6539
PURE UUID: 57a67485-a3f7-4ca8-b0ca-1594371853b4
Catalogue record
Date deposited: 14 Mar 2011 10:17
Last modified: 14 Mar 2024 02:51
Export record
Altmetrics
Contributors
Author:
Douglas S. Shephard
Author:
Thomas Maschmeyer
Author:
Gopinathan Sankar
Author:
John Meurig Thomas
Author:
Dogan Ozkaya
Author:
Brian F.G. Johnson
Author:
Richard D. Oldroyd
Author:
Robert G. Bell
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics
