Quantum translator-rotator: Inelastic neutron scattering of dihydrogen molecules trapped inside anisotropic fullerene cages
Quantum translator-rotator: Inelastic neutron scattering of dihydrogen molecules trapped inside anisotropic fullerene cages
We report an inelastic neutron scattering investigation of the quantum dynamics of hydrogen molecules trapped inside anisotropic fullerene cages. Transitions among the manifold of quantized rotational and translational states are directly observed. The spectra recorded as a function of energy and momentum transfer are interpreted in terms of the rotational potential and the cage dimensions. The thermodynamics of orthohydrogen and parahydrogen are investigated through temperature dependence measurements.
13001
Horsewill, A.J.
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Panesar, K.S.
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Rols, S.
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Johnson, M.R.
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Murata, Y.
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Komatsu, K.
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Mamone, S.
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Danquigny, A.
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Cuda, F.
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Maltsev, S.
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Grossel, M.C.
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Carravetta, M.
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Levitt, M.H.
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5 January 2009
Horsewill, A.J.
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Panesar, K.S.
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Rols, S.
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Johnson, M.R.
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Murata, Y.
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Komatsu, K.
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Mamone, S.
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Danquigny, A.
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Cuda, F.
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Maltsev, S.
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Grossel, M.C.
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Carravetta, M.
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Levitt, M.H.
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Horsewill, A.J., Panesar, K.S., Rols, S., Johnson, M.R., Murata, Y., Komatsu, K., Mamone, S., Danquigny, A., Cuda, F., Maltsev, S., Grossel, M.C., Carravetta, M. and Levitt, M.H.
(2009)
Quantum translator-rotator: Inelastic neutron scattering of dihydrogen molecules trapped inside anisotropic fullerene cages.
Physical Review Letters, 102 (1), .
(doi:10.1103/PhysRevLett.102.013001).
Abstract
We report an inelastic neutron scattering investigation of the quantum dynamics of hydrogen molecules trapped inside anisotropic fullerene cages. Transitions among the manifold of quantized rotational and translational states are directly observed. The spectra recorded as a function of energy and momentum transfer are interpreted in terms of the rotational potential and the cage dimensions. The thermodynamics of orthohydrogen and parahydrogen are investigated through temperature dependence measurements.
Text
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Published date: 5 January 2009
Organisations:
Chemistry, Magnetic Resonance
Identifiers
Local EPrints ID: 178397
URI: http://eprints.soton.ac.uk/id/eprint/178397
PURE UUID: 22818f86-34d7-47d4-89a5-2cff70a14fa8
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Date deposited: 24 Mar 2011 12:16
Last modified: 15 Mar 2024 03:08
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Contributors
Author:
A.J. Horsewill
Author:
K.S. Panesar
Author:
S. Rols
Author:
M.R. Johnson
Author:
Y. Murata
Author:
K. Komatsu
Author:
S. Mamone
Author:
A. Danquigny
Author:
F. Cuda
Author:
S. Maltsev
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