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Polymorphism in pyridine-2,6-dicarboxylic acid: Competition between “robust” synthons

Polymorphism in pyridine-2,6-dicarboxylic acid: Competition between “robust” synthons
Polymorphism in pyridine-2,6-dicarboxylic acid: Competition between “robust” synthons
A new polymorph of anhydrous pyridine-2,6-dicarboxylic (dipicolinic) acid in which salt formation is favoured over carboxylic acid dimerisation is reported, together with the solid-state architectures of a novel dipicolinic acid dihydrate and a monohydrate structure of the 4-chloro analogue.


1466-8033
123-128
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Dwyer, Andrew N.
a8d19fdc-08a2-4bc0-902c-5fb1b0582fd9
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f
Grossel, Martin C.
403bf3ff-6364-44e9-ab46-52d84c6f0d56
Dwyer, Andrew N.
a8d19fdc-08a2-4bc0-902c-5fb1b0582fd9
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Orton, James B.
4e2a471f-9e11-4cb4-abb6-d0398047939f

Grossel, Martin C., Dwyer, Andrew N., Hursthouse, Michael B. and Orton, James B. (2006) Polymorphism in pyridine-2,6-dicarboxylic acid: Competition between “robust” synthons. CrystEngComm, 8 (2), 123-128. (doi:10.1039/B516387K).

Record type: Article

Abstract

A new polymorph of anhydrous pyridine-2,6-dicarboxylic (dipicolinic) acid in which salt formation is favoured over carboxylic acid dimerisation is reported, together with the solid-state architectures of a novel dipicolinic acid dihydrate and a monohydrate structure of the 4-chloro analogue.


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Published date: 2006

Identifiers

Local EPrints ID: 178889
URI: http://eprints.soton.ac.uk/id/eprint/178889
ISSN: 1466-8033
PURE UUID: d8e74099-c9db-44ed-bfab-e7b94cf527cf
ORCID for Martin C. Grossel: ORCID iD orcid.org/0000-0001-7469-6854

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Date deposited: 28 Mar 2011 13:09
Last modified: 10 Dec 2019 01:56

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