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Direct determination of diffusion coefficients by chronoamperometry at microdisk electrodes

Denuault, Guy, Mirkin, Michael V. and Bard, Allen J. (1991) Direct determination of diffusion coefficients by chronoamperometry at microdisk electrodes Journal of Electroanalytical Chemistry, 308, (1-2), pp. 27-38. (doi:10.1016/0022-0728(91)85056-U).

Record type: Article

Abstract

The chronoamperometric response at a microdisk is used for the direct determination of the diffusion coefficient of an electroactive species. The method does not require knowledge of the bulk concentration and the number of electrons participating in the electrode reaction, and requires only a value for the disk radius. Subsequent determination of the number of electrons (n) for an electrode reaction or the concentration of electroactive species is also possible. This approach is demonstrated with the evaluation of the diffusion coefficient of Fe(CN)6(4-) in KCl and that of borohydride ion in NaOH. In both cases, the values of n found remained constant over a wide time range and correspond to those expected for these processes.

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Published date: 25 June 1991
Additional Information: FV724

Identifiers

Local EPrints ID: 179279
URI: http://eprints.soton.ac.uk/id/eprint/179279
ISSN: 1572-6657
PURE UUID: 16b5867c-7525-4f6d-90b9-aa278ed2ecec
ORCID for Guy Denuault: ORCID iD orcid.org/0000-0002-8630-9492

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Date deposited: 31 Mar 2011 13:58
Last modified: 18 Jul 2017 12:03

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Contributors

Author: Guy Denuault ORCID iD
Author: Michael V. Mirkin
Author: Allen J. Bard

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