closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies

Terrasson, Vincent, Planas, José Giner, Viñas, Clara, Teixidor, Francesc, Prim, Damien, Light, Mark E. and Hursthouse, Michael B. (2010) closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies. Organometallics, 29 (18), 4130-4134. (doi:10.1021/om1006374).

Abstract

The synthesis of new pyridine-substituted carboranylmethylamines is described. The strategy involved mesylation of carboranylmethanols prior to amination reaction and is particularly adapted to the reactivity of o-carborane derivatives bearing a 2-pyridinyl substituent. Preparation and characterization of a corresponding N,N-ligand?palladium complex as well as first results in a Suzuki coupling reaction are illustrated.

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Contributors

Author: Mark E. Light

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