The University of Southampton
University of Southampton Institutional Repository

closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies

closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies
closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies
The synthesis of new pyridine-substituted carboranylmethylamines is described. The strategy involved mesylation of carboranylmethanols prior to amination reaction and is particularly adapted to the reactivity of o-carborane derivatives bearing a 2-pyridinyl substituent. Preparation and characterization of a corresponding N,N-ligand?palladium complex as well as first results in a Suzuki coupling reaction are illustrated.
0276-7333
4130-4134
Terrasson, Vincent
28abd553-801c-415a-a09f-ff32adb54107
Planas, José Giner
bf835e30-8f70-4675-9438-5a10c9bc9880
Viñas, Clara
95bb80c2-e34c-41bf-bd88-d54a5e587b83
Teixidor, Francesc
d24b81b5-5d82-42ca-bd30-fd9c73d0ee68
Prim, Damien
0f74e921-8f1c-4916-830f-36f0cc5f85f9
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Terrasson, Vincent
28abd553-801c-415a-a09f-ff32adb54107
Planas, José Giner
bf835e30-8f70-4675-9438-5a10c9bc9880
Viñas, Clara
95bb80c2-e34c-41bf-bd88-d54a5e587b83
Teixidor, Francesc
d24b81b5-5d82-42ca-bd30-fd9c73d0ee68
Prim, Damien
0f74e921-8f1c-4916-830f-36f0cc5f85f9
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Terrasson, Vincent, Planas, José Giner, Viñas, Clara, Teixidor, Francesc, Prim, Damien, Light, Mark E. and Hursthouse, Michael B. (2010) closo-o-carboranylmethylamine?pyridine associations: synthesis, characterization, and first complexation studies. Organometallics, 29 (18), 4130-4134. (doi:10.1021/om1006374).

Record type: Article

Abstract

The synthesis of new pyridine-substituted carboranylmethylamines is described. The strategy involved mesylation of carboranylmethanols prior to amination reaction and is particularly adapted to the reactivity of o-carborane derivatives bearing a 2-pyridinyl substituent. Preparation and characterization of a corresponding N,N-ligand?palladium complex as well as first results in a Suzuki coupling reaction are illustrated.

Full text not available from this repository.

More information

Published date: 27 September 2010

Identifiers

Local EPrints ID: 179395
URI: http://eprints.soton.ac.uk/id/eprint/179395
ISSN: 0276-7333
PURE UUID: c68ce130-c7d8-45df-b337-e33d3ba2e6cb
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

Catalogue record

Date deposited: 01 Apr 2011 08:31
Last modified: 07 Oct 2020 07:23

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×