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Unusual aryl migration in a mesomeric betaine in the solid and liquid state: mechanistic insights into the SNAr reaction

Unusual aryl migration in a mesomeric betaine in the solid and liquid state: mechanistic insights into the SNAr reaction
Unusual aryl migration in a mesomeric betaine in the solid and liquid state: mechanistic insights into the SNAr reaction
An intramolecular SNAr mechanism has been identified in the unexpected aryl migration observed in a mesomeric betaine. The process changes drastically the optical and spectroscopic properties and should be a valuable model for related heteroaromatic systems
0022-3263
4300-4303
Cantillo, David
87273376-7777-4726-bbf9-505104580fad
Ávalos, Martín
472f15e9-0c05-4b63-9566-e3d6e6e70329
Babiano, Reyes
b7ffd91c-bacd-4372-ab99-fc30ac2450ae
Cintas, Pedro
29979233-8382-47a8-bde7-1faf4869308c
Jiménez, José L.
2805f32b-fcee-49fa-8746-53a38ddd40a1
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Palacios, Juan C.
2c06e379-89b3-46b1-95c8-7f5057732f9f
Cantillo, David
87273376-7777-4726-bbf9-505104580fad
Ávalos, Martín
472f15e9-0c05-4b63-9566-e3d6e6e70329
Babiano, Reyes
b7ffd91c-bacd-4372-ab99-fc30ac2450ae
Cintas, Pedro
29979233-8382-47a8-bde7-1faf4869308c
Jiménez, José L.
2805f32b-fcee-49fa-8746-53a38ddd40a1
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Palacios, Juan C.
2c06e379-89b3-46b1-95c8-7f5057732f9f

Cantillo, David, Ávalos, Martín, Babiano, Reyes, Cintas, Pedro, Jiménez, José L., Light, Mark E. and Palacios, Juan C. (2010) Unusual aryl migration in a mesomeric betaine in the solid and liquid state: mechanistic insights into the SNAr reaction. Journal of Organic Chemistry, 75 (12), 4300-4303. (doi:10.1021/jo100350t). (PMID:20481589)

Record type: Article

Abstract

An intramolecular SNAr mechanism has been identified in the unexpected aryl migration observed in a mesomeric betaine. The process changes drastically the optical and spectroscopic properties and should be a valuable model for related heteroaromatic systems

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Published date: June 2010

Identifiers

Local EPrints ID: 179431
URI: https://eprints.soton.ac.uk/id/eprint/179431
ISSN: 0022-3263
PURE UUID: 97925e1d-056f-4677-ac3f-d3b08a7b2e0f
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843

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Date deposited: 01 Apr 2011 10:39
Last modified: 06 Jun 2018 12:54

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