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A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin

Hu, Yulai and Brown, Richard C. D. (2005) A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin Chemical Communications, 45, (45), pp. 5636-5637. (doi:10.1039/B512126d). (PMID:16292373).

Record type: Article

Abstract

A synthesis of 21,22-diepi-membrarollin ( 14) is described, which employed sequential metal-oxo mediated oxidative cyclisations to introduce six of the seven stereogenic centres.

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Published date: 2005
Keywords: promoted oxidative cyclization, annonaceous acetogenins, stereoselective synthesis, permanganate oxidation, polyether teurilene, rhenium(vii) oxides, cis-solamin, 1, 5-dienes, polycyclizations, stereochemistry
Organisations: Chemistry

Identifiers

Local EPrints ID: 180737
URI: http://eprints.soton.ac.uk/id/eprint/180737
ISSN: 1359-7345
PURE UUID: 5e76e35f-10bd-43fa-b39d-6b0d101e22c0
ORCID for Richard C. D. Brown: ORCID iD orcid.org/0000-0003-0156-7087

Catalogue record

Date deposited: 12 May 2011 09:04
Last modified: 18 Jul 2017 12:00

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Contributors

Author: Yulai Hu

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