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A rapid-doping method for high-throughput discovery applied to thick- film PTCR materials

A rapid-doping method for high-throughput discovery applied to thick- film PTCR materials
A rapid-doping method for high-throughput discovery applied to thick- film PTCR materials
A novel high-throughput combinatorial library preparation technique for ceramics requiring low levels of dopant is demonstrated and assessed for the case of donor-doped barium titanate (BT) materials with positive temperature coefficient of resistance (PTCR) materials. The droplet-doping process is performed by infiltrating liquid dopant precursors into porous BT disks and viewed by high speed camera. The resulting dopant distribution in the body of the disk shows high uniformity as assessed by energy dispersive (EDS) and wavelength dispersive (WDS) spectroscopies. X-ray diffraction (XRD) measurements and resistivity-temperature (?-T) curves show evidence of the changes in structure and PTCR profiles with change in composition and are closely matched to previously published data for samples made by conventional ceramic routes. The procedure, thus validated, has the potential to deliver dopant-doped BT-based PTCR libraries rapidly with a very wide range of dopant mixtures and concentrations for electrical property measurement and deserves to be applied to other low level dopant ceramic systems.
droplet doping, high throughput, PTCR, infiltration, barium titanate, droplet-printing
0002-7820
3748-3756
Chen, Yulong
c169c2b5-8f32-4857-8436-42acf15d9ce8
Evans, Julian RG
3bfd4eb9-7a29-4164-8966-937df60160cb
Yang, Shoufeng
e0018adf-8123-4a54-b8dd-306c10ca48f1
Chen, Yulong
c169c2b5-8f32-4857-8436-42acf15d9ce8
Evans, Julian RG
3bfd4eb9-7a29-4164-8966-937df60160cb
Yang, Shoufeng
e0018adf-8123-4a54-b8dd-306c10ca48f1

Chen, Yulong, Evans, Julian RG and Yang, Shoufeng (2011) A rapid-doping method for high-throughput discovery applied to thick- film PTCR materials. Journal of the American Ceramic Society, 94 (11), 3748-3756. (doi:10.1111/j.1551-2916.2011.04667.x).

Record type: Article

Abstract

A novel high-throughput combinatorial library preparation technique for ceramics requiring low levels of dopant is demonstrated and assessed for the case of donor-doped barium titanate (BT) materials with positive temperature coefficient of resistance (PTCR) materials. The droplet-doping process is performed by infiltrating liquid dopant precursors into porous BT disks and viewed by high speed camera. The resulting dopant distribution in the body of the disk shows high uniformity as assessed by energy dispersive (EDS) and wavelength dispersive (WDS) spectroscopies. X-ray diffraction (XRD) measurements and resistivity-temperature (?-T) curves show evidence of the changes in structure and PTCR profiles with change in composition and are closely matched to previously published data for samples made by conventional ceramic routes. The procedure, thus validated, has the potential to deliver dopant-doped BT-based PTCR libraries rapidly with a very wide range of dopant mixtures and concentrations for electrical property measurement and deserves to be applied to other low level dopant ceramic systems.

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drop_doping_30_09_2012_eprint.doc - Accepted Manuscript
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More information

Published date: 20 July 2011
Keywords: droplet doping, high throughput, PTCR, infiltration, barium titanate, droplet-printing
Organisations: Engineering Mats & Surface Engineerg Gp

Identifiers

Local EPrints ID: 187435
URI: http://eprints.soton.ac.uk/id/eprint/187435
ISSN: 0002-7820
PURE UUID: b60f7521-be1a-4eb6-8691-7ecdffaf5cf8
ORCID for Shoufeng Yang: ORCID iD orcid.org/0000-0002-3888-3211

Catalogue record

Date deposited: 17 May 2011 12:07
Last modified: 14 Mar 2024 03:25

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Contributors

Author: Yulong Chen
Author: Julian RG Evans
Author: Shoufeng Yang ORCID iD

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