Total spontaneous resolution of a cyanoguanidine showing only conformational chirality
Total spontaneous resolution of a cyanoguanidine showing only conformational chirality
The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.
absolute asymmetric-synthesis, solid-state, crystal environment, amide
61-62
Cunningham, I. D.
7e636eb2-301a-4485-9fc1-3ea7c4a2cac1
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
2000
Cunningham, I. D.
7e636eb2-301a-4485-9fc1-3ea7c4a2cac1
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Cunningham, I. D., Coles, S. J. and Hursthouse, M. B.
(2000)
Total spontaneous resolution of a cyanoguanidine showing only conformational chirality.
Chemical Communications, (1), .
(doi:10.1039/a907518f).
Abstract
The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.
This record has no associated files available for download.
More information
Published date: 2000
Keywords:
absolute asymmetric-synthesis, solid-state, crystal environment, amide
Identifiers
Local EPrints ID: 18851
URI: http://eprints.soton.ac.uk/id/eprint/18851
ISSN: 1359-7345
PURE UUID: 1a62254e-5768-40fb-b7a1-e8b626203322
Catalogue record
Date deposited: 20 Dec 2005
Last modified: 15 Mar 2024 06:08
Export record
Altmetrics
Contributors
Author:
I. D. Cunningham
Author:
S. J. Coles
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.
View more statistics