Cunningham, I. D., Coles, S. J. and Hursthouse, M. B.
Total spontaneous resolution of a cyanoguanidine showing only conformational chirality
Chemical Communications, (1), . (doi:10.1039/a907518f).
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The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.
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