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Total spontaneous resolution of a cyanoguanidine showing only conformational chirality

Cunningham, I. D., Coles, S. J. and Hursthouse, M. B. (2000) Total spontaneous resolution of a cyanoguanidine showing only conformational chirality Chemical Communications, (1), pp. 61-62. (doi:10.1039/a907518f).

Record type: Article


The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.

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Published date: 2000
Keywords: absolute asymmetric-synthesis, solid-state, crystal environment, amide


Local EPrints ID: 18851
ISSN: 1359-7345
PURE UUID: 1a62254e-5768-40fb-b7a1-e8b626203322

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Date deposited: 20 Dec 2005
Last modified: 17 Jul 2017 16:34

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Author: I. D. Cunningham
Author: S. J. Coles
Author: M. B. Hursthouse

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