Synthesis and properties of thallium(III) periodate
Synthesis and properties of thallium(III) periodate
The reaction of [T1(H2O)(6)](3 +) with H5IO6 in aqueous acid solution over a range Tl-5(IO6)(3), which has been characterised by analysis, IR and UV-Vis spectroscopy The compound is amorphous, but I K- and Tl L-III edge EXAFS studies identify IO6 and TlO6 as the structural units present and a possible structure is proposed. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes.
thallium periodate, exafscomplexes
116-119
Binsted, N.
65feae77-d851-4edd-9509-48a65ede85d8
Hector, A. L.
6f6eb516-cc99-4bb6-82ab-be981316f585
Levason, W.
2388863a-5332-4ce5-8264-572fd8ee7d82
30 January 2000
Binsted, N.
65feae77-d851-4edd-9509-48a65ede85d8
Hector, A. L.
6f6eb516-cc99-4bb6-82ab-be981316f585
Levason, W.
2388863a-5332-4ce5-8264-572fd8ee7d82
Binsted, N., Hector, A. L. and Levason, W.
(2000)
Synthesis and properties of thallium(III) periodate.
Inorganica Chimica Acta, 298 (1), .
(doi:10.1016/S0020-1693(99)00427-2).
Abstract
The reaction of [T1(H2O)(6)](3 +) with H5IO6 in aqueous acid solution over a range Tl-5(IO6)(3), which has been characterised by analysis, IR and UV-Vis spectroscopy The compound is amorphous, but I K- and Tl L-III edge EXAFS studies identify IO6 and TlO6 as the structural units present and a possible structure is proposed. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes.
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Published date: 30 January 2000
Keywords:
thallium periodate, exafscomplexes
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Local EPrints ID: 18880
URI: http://eprints.soton.ac.uk/id/eprint/18880
ISSN: 0020-1693
PURE UUID: 7d556a96-3294-4892-ae16-fd365fca1034
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Date deposited: 03 Jan 2006
Last modified: 15 Mar 2024 06:08
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Author:
N. Binsted
Author:
A. L. Hector
Author:
W. Levason
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