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Synthesis and properties of thallium(III) periodate

Binsted, N., Hector, A. L. and Levason, W. (2000) Synthesis and properties of thallium(III) periodate Inorganica Chimica Acta, 298, (1), pp. 116-119. (doi:10.1016/S0020-1693(99)00427-2).

Record type: Article

Abstract

The reaction of [T1(H2O)(6)](3 +) with H5IO6 in aqueous acid solution over a range Tl-5(IO6)(3), which has been characterised by analysis, IR and UV-Vis spectroscopy The compound is amorphous, but I K- and Tl L-III edge EXAFS studies identify IO6 and TlO6 as the structural units present and a possible structure is proposed. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. (C) 2000 Elsevier Science S.A. All rights reserved.

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Published date: 30 January 2000
Keywords: thallium periodate, exafs complexes

Identifiers

Local EPrints ID: 18880
URI: http://eprints.soton.ac.uk/id/eprint/18880
ISSN: 0020-1693
PURE UUID: 7d556a96-3294-4892-ae16-fd365fca1034

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Date deposited: 03 Jan 2006
Last modified: 17 Jul 2017 16:34

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Contributors

Author: N. Binsted
Author: A. L. Hector
Author: W. Levason

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