Binsted, N., Hector, A. L. and Levason, W.
Synthesis and properties of thallium(III) periodate
Inorganica Chimica Acta, 298, (1), . (doi:10.1016/S0020-1693(99)00427-2).
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The reaction of [T1(H2O)(6)](3 +) with H5IO6 in aqueous acid solution over a range Tl-5(IO6)(3), which has been characterised by analysis, IR and UV-Vis spectroscopy The compound is amorphous, but I K- and Tl L-III edge EXAFS studies identify IO6 and TlO6 as the structural units present and a possible structure is proposed. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. (C) 2000 Elsevier Science S.A. All rights reserved.
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