The structure of ethylbenzene as a solute in liquid crystalline solvents via analysis of proton NMR spectra
The structure of ethylbenzene as a solute in liquid crystalline solvents via analysis of proton NMR spectra
Previous attempts to analyze the proton spectrum of ethylbenzene as a solute in nematic liquid crystalline solvents failed, but a successful strategy has now been devised and is described here. The proton spectra of samples of ethylbenzene dissolved in four different liquid crystals have been analyzed to yield sets of the partially-averaged dipolar couplings, D-ij. The couplings are then used to test models for the structure and conformation of this molecule.
samples
3405-3413
Algieri, C.
170db547-304b-4a00-9e2f-1f0cb14cfb89
Castiglione, F.
60b8b50f-41b0-4c64-99c5-d553edcea838
Celebre, G.
75851a36-1291-4c3c-bea7-b1442d0016b0
De Luca, G.
b190a7b3-3729-4118-b4c7-3a04da54f2b8
Longeri, M.
39ff086e-7606-4a08-9296-1528644fdef5
Emsley, J. W.
1196f183-5b1c-4948-8f59-e67c0710406e
2000
Algieri, C.
170db547-304b-4a00-9e2f-1f0cb14cfb89
Castiglione, F.
60b8b50f-41b0-4c64-99c5-d553edcea838
Celebre, G.
75851a36-1291-4c3c-bea7-b1442d0016b0
De Luca, G.
b190a7b3-3729-4118-b4c7-3a04da54f2b8
Longeri, M.
39ff086e-7606-4a08-9296-1528644fdef5
Emsley, J. W.
1196f183-5b1c-4948-8f59-e67c0710406e
Algieri, C., Castiglione, F., Celebre, G., De Luca, G., Longeri, M. and Emsley, J. W.
(2000)
The structure of ethylbenzene as a solute in liquid crystalline solvents via analysis of proton NMR spectra.
Physical Chemistry Chemical Physics, 2 (15), .
(doi:10.1039/b002803g).
Abstract
Previous attempts to analyze the proton spectrum of ethylbenzene as a solute in nematic liquid crystalline solvents failed, but a successful strategy has now been devised and is described here. The proton spectra of samples of ethylbenzene dissolved in four different liquid crystals have been analyzed to yield sets of the partially-averaged dipolar couplings, D-ij. The couplings are then used to test models for the structure and conformation of this molecule.
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Published date: 2000
Keywords:
samples
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Local EPrints ID: 18902
URI: http://eprints.soton.ac.uk/id/eprint/18902
ISSN: 1463-9076
PURE UUID: 7ff49891-fa50-46e4-a1c2-ac9d15f03c90
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Date deposited: 05 Jan 2006
Last modified: 15 Mar 2024 06:09
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Contributors
Author:
C. Algieri
Author:
F. Castiglione
Author:
G. Celebre
Author:
G. De Luca
Author:
M. Longeri
Author:
J. W. Emsley
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