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A selenide linker for "traceless" solid-phase organic synthesis

Record type: Article

4-Bromophenethyl alcohol was protected as the THP ether, followed by reaction with magnesium and selenium to give the corresponding diselenide. Ether deprotection provides a diselenide diol, which is attached to solid-phase resins. The polymer-bound selenide anion is then generated, and functions as a traceless linker for electrophiles such as alkyl halides.

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Citation

Li, Z. G., Kulkarni, B. A. and Ganesan, A. (2000) A selenide linker for "traceless" solid-phase organic synthesis Biotechnology and Bioengineering, 71, (2), pp. 104-106. (doi:10.1002/1097-0290(2000)71:2<104::AID-BIT1000>3.0.CO;2-7).

More information

Published date: 2000
Keywords: solid-phase synthesis, traceless linkers, selenides strategies, cleavage

Identifiers

Local EPrints ID: 18917
URI: http://eprints.soton.ac.uk/id/eprint/18917
ISSN: 0006-3592
PURE UUID: e68a84dc-2ab0-412f-913c-e251f6546c4a

Catalogue record

Date deposited: 18 Jan 2006
Last modified: 17 Jul 2017 16:34

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Contributors

Author: Z. G. Li
Author: B. A. Kulkarni
Author: A. Ganesan

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