Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework
Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework
Radical cascade cyclisation of methylenecyclopropyl cyclohexanone adducts, using samarium diiodide to generate an initial ketyl radical, provide a short route to tricyclic ethers, and the stereochemical outcome can be influenced by the solvent used for the reaction.
methylenecyclopropane, samarium diiodide, cascade radical cyclisation
cyclization reactions, iodide
10341-10345
Watson, F. C.
567add92-8e9d-4fa2-9291-17ca825f98da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
23 December 2000
Watson, F. C.
567add92-8e9d-4fa2-9291-17ca825f98da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
Watson, F. C. and Kilburn, J. D.
(2000)
Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework.
Tetrahedron Letters, 41 (52), .
(doi:10.1016/S0040-4039(00)01859-1).
Abstract
Radical cascade cyclisation of methylenecyclopropyl cyclohexanone adducts, using samarium diiodide to generate an initial ketyl radical, provide a short route to tricyclic ethers, and the stereochemical outcome can be influenced by the solvent used for the reaction.
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Published date: 23 December 2000
Keywords:
methylenecyclopropane, samarium diiodide, cascade radical cyclisation
cyclization reactions, iodide
Identifiers
Local EPrints ID: 18918
URI: http://eprints.soton.ac.uk/id/eprint/18918
ISSN: 0040-4039
PURE UUID: 00df9dd9-bbde-47d3-bf85-cc7b02d2f2a0
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Date deposited: 15 Dec 2005
Last modified: 15 Mar 2024 06:09
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Contributors
Author:
F. C. Watson
Author:
J. D. Kilburn
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