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Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework

Watson, F. C. and Kilburn, J. D. (2000) Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework Tetrahedron Letters, 41, (52), pp. 10341-10345. (doi:10.1016/S0040-4039(00)01859-1).

Record type: Article

Abstract

Radical cascade cyclisation of methylenecyclopropyl cyclohexanone adducts, using samarium diiodide to generate an initial ketyl radical, provide a short route to tricyclic ethers, and the stereochemical outcome can be influenced by the solvent used for the reaction.

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More information

Published date: 23 December 2000
Keywords: methylenecyclopropane, samarium diiodide, cascade radical cyclisation cyclization reactions, iodide

Identifiers

Local EPrints ID: 18918
URI: http://eprints.soton.ac.uk/id/eprint/18918
ISSN: 0040-4039
PURE UUID: 00df9dd9-bbde-47d3-bf85-cc7b02d2f2a0

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Date deposited: 15 Dec 2005
Last modified: 17 Jul 2017 16:34

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Contributors

Author: F. C. Watson
Author: J. D. Kilburn

University divisions

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