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Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of [Rh(CO)2Cl]2

Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of [Rh(CO)2Cl]2
Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of [Rh(CO)2Cl]2
Room temperature adsorption of [Rh(CO)2Cl]2 on TiO2[110] is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)2Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.
geminal dicarbonyl, co, no, tio2(110), adsorbates, catalysts, chlorine, surface, stm
1359-7345
1677-1678
Newton, M.A.
c2955c76-361e-4cfd-bea1-e66ec3ae7ce4
Bennett, R.A.
dde6d32b-6800-4f01-89a3-4462b186a65a
Smith, R.D.
6b20c264-0d74-4701-8a9c-83c4def46350
Bowker, M.
8e99ffe0-6f5e-442e-a30a-158afaa3f85c
Evans, J.
05890433-0155-49fe-a65d-38c90ea25c69
Newton, M.A.
c2955c76-361e-4cfd-bea1-e66ec3ae7ce4
Bennett, R.A.
dde6d32b-6800-4f01-89a3-4462b186a65a
Smith, R.D.
6b20c264-0d74-4701-8a9c-83c4def46350
Bowker, M.
8e99ffe0-6f5e-442e-a30a-158afaa3f85c
Evans, J.
05890433-0155-49fe-a65d-38c90ea25c69

Newton, M.A., Bennett, R.A., Smith, R.D., Bowker, M. and Evans, J. (2000) Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of [Rh(CO)2Cl]2. Chemical Communications, (17), 1677-1678. (doi:10.1039/b003782f).

Record type: Article

Abstract

Room temperature adsorption of [Rh(CO)2Cl]2 on TiO2[110] is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)2Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.

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More information

Published date: 2000
Keywords: geminal dicarbonyl, co, no, tio2(110), adsorbates, catalysts, chlorine, surface, stm

Identifiers

Local EPrints ID: 18920
URI: http://eprints.soton.ac.uk/id/eprint/18920
ISSN: 1359-7345
PURE UUID: f1402dd6-171d-44aa-a623-da78610c6260

Catalogue record

Date deposited: 20 Dec 2005
Last modified: 03 Jan 2019 10:30

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