Newton, M. A., Bennett, R. A., Smith, R. D., Bowker, M. and Evans, J.
Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of Rh(CO)(2)Cl (2)
Chemical Communications, (17), . (doi:10.1039/b003782f).
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Room temperature adsorption of [Rh(CO)(2)Cl](2) on TiO2 is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)(2)Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.
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