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RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure

RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure
RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure
The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1:1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu-O 1.89-1.95 Angstrom) tetrahedra; a second metastable very pale green-blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.
zeolite abw, phases
1359-7345
1959-1960
Henry, P. F.
329d2dd7-c37b-44d9-9fc1-6583b36deed2
Hughes, R. W.
0bc55aee-91da-4108-b115-73df02928e2b
Ward, S. C.
0480d245-5298-4a0f-8765-20ed57ae4099
Weller, M. T.
186aa097-9fd5-4c08-88a1-5359c3318c85
Henry, P. F.
329d2dd7-c37b-44d9-9fc1-6583b36deed2
Hughes, R. W.
0bc55aee-91da-4108-b115-73df02928e2b
Ward, S. C.
0480d245-5298-4a0f-8765-20ed57ae4099
Weller, M. T.
186aa097-9fd5-4c08-88a1-5359c3318c85

Henry, P. F., Hughes, R. W., Ward, S. C. and Weller, M. T. (2000) RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure. Chemical Communications, (19), 1959-1960. (doi:10.1039/b006429g).

Record type: Article

Abstract

The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1:1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu-O 1.89-1.95 Angstrom) tetrahedra; a second metastable very pale green-blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.

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More information

Published date: 2000
Keywords: zeolite abw, phases

Identifiers

Local EPrints ID: 18930
URI: https://eprints.soton.ac.uk/id/eprint/18930
ISSN: 1359-7345
PURE UUID: d6979197-efad-4269-b607-2fab17046f7c

Catalogue record

Date deposited: 20 Dec 2005
Last modified: 17 Jul 2017 16:34

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