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Pyridine functionalised N-heterocyclic carbene complexes of palladium

Tulloch, A. A. D., Danopoulos, A. A., Tooze, R. P., Cafferkey, S. M., Kleinhenz, S. and Hursthouse, M. B. (2000) Pyridine functionalised N-heterocyclic carbene complexes of palladium Chemical Communications, (14), pp. 1247-1248. (doi:10.1039/b002645j).

Record type: Article


The pyridine functionalised N-heterocyclic carbene complexes (C-N)PdMeBr, C-N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = Bu-t 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C-N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C-N)](4) framework with bridging C-N ligands.

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Published date: 2000
Keywords: olefin metathesis, catalysts


Local EPrints ID: 18933
ISSN: 1359-7345
PURE UUID: f9c0477a-5fee-49b6-8a4a-c2283c50017a

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Date deposited: 20 Dec 2005
Last modified: 17 Jul 2017 16:34

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Author: A. A. D. Tulloch
Author: A. A. Danopoulos
Author: R. P. Tooze
Author: S. M. Cafferkey
Author: S. Kleinhenz
Author: M. B. Hursthouse

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