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Pyridine functionalised N-heterocyclic carbene complexes of palladium

Pyridine functionalised N-heterocyclic carbene complexes of palladium
Pyridine functionalised N-heterocyclic carbene complexes of palladium
The pyridine functionalised N-heterocyclic carbene complexes (C-N)PdMeBr, C-N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = Bu-t 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C-N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C-N)](4) framework with bridging C-N ligands.
olefin metathesis, catalysts
1359-7345
1247-1248
Tulloch, A. A. D.
8fe08eb4-a6f5-4ebb-b0a4-19fc745a018a
Danopoulos, A. A.
b3cd9aa6-4a49-45d8-8cb6-72b1d2a441a7
Tooze, R. P.
b578b9e7-9ca8-4a6b-8f2d-aa30db92df09
Cafferkey, S. M.
5d32ccbc-f596-426b-a580-b0bd754f1e41
Kleinhenz, S.
d42fbac0-9883-4858-a271-c969e8b8c2bc
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Tulloch, A. A. D.
8fe08eb4-a6f5-4ebb-b0a4-19fc745a018a
Danopoulos, A. A.
b3cd9aa6-4a49-45d8-8cb6-72b1d2a441a7
Tooze, R. P.
b578b9e7-9ca8-4a6b-8f2d-aa30db92df09
Cafferkey, S. M.
5d32ccbc-f596-426b-a580-b0bd754f1e41
Kleinhenz, S.
d42fbac0-9883-4858-a271-c969e8b8c2bc
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da

Tulloch, A. A. D., Danopoulos, A. A., Tooze, R. P., Cafferkey, S. M., Kleinhenz, S. and Hursthouse, M. B. (2000) Pyridine functionalised N-heterocyclic carbene complexes of palladium. Chemical Communications, (14), 1247-1248. (doi:10.1039/b002645j).

Record type: Article

Abstract

The pyridine functionalised N-heterocyclic carbene complexes (C-N)PdMeBr, C-N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = Bu-t 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C-N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C-N)](4) framework with bridging C-N ligands.

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More information

Published date: 2000
Keywords: olefin metathesis, catalysts

Identifiers

Local EPrints ID: 18933
URI: http://eprints.soton.ac.uk/id/eprint/18933
ISSN: 1359-7345
PURE UUID: f9c0477a-5fee-49b6-8a4a-c2283c50017a

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Date deposited: 20 Dec 2005
Last modified: 15 Mar 2024 06:09

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Contributors

Author: A. A. D. Tulloch
Author: A. A. Danopoulos
Author: R. P. Tooze
Author: S. M. Cafferkey
Author: S. Kleinhenz

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