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A novel chiral distibine-centred polyimido anion

Record type: Article

Reaction of (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2) with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb](2)(mu-NR)(CH2)(3).(RNHLi). 3THF (1), incorporating the co-complexation of primary lithium amide; the X-ray crystal structure of 1 reveals a bimetallic imido-/amido-bridged cage structure of interlocking 6-membered rings, crystallising as a single enantiomer.

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Citation

Coles, S. J., Hursthouse, M. B., Joy, J. S. and Paver, M. A. (2000) A novel chiral distibine-centred polyimido anion Journal of the Chemical Society Dalton Transactions, (19), pp. 3239-3241. (doi:10.1039/b007031i).

More information

Published date: 2000
Keywords: complex

Identifiers

Local EPrints ID: 18945
URI: http://eprints.soton.ac.uk/id/eprint/18945
ISSN: 1472-7773
PURE UUID: 0afa0d85-d24a-4d97-80eb-47b29b2725a6

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Date deposited: 20 Dec 2005
Last modified: 17 Jul 2017 16:34

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Contributors

Author: S. J. Coles
Author: M. B. Hursthouse
Author: J. S. Joy
Author: M. A. Paver

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