New macrobicyclic receptors for amino acids
New macrobicyclic receptors for amino acids
Two new receptors, 9 and 13, have been prepared, utilising a pyridyl aryl ether unit in the rim of the macrobicyclic structure, and the crystal structures for both of these receptors are reported. The presence of the pyridyl unit provides additional hydrogen bonding functionality in comparison to earlier structures of this type, and 9 is an effective receptor for N-acetyl L-asparagine carboxylate in CH2Cl2.
host-guest, receptor, amino acid
identification, derivatives, sequence, peptides
3963-3966
Jullian, V.
40d197a8-05c9-432d-931c-d46b79b22d9d
Shepherd, E.
c4326e11-f31b-4433-8f87-5b97934db7ac
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
21 May 2000
Jullian, V.
40d197a8-05c9-432d-931c-d46b79b22d9d
Shepherd, E.
c4326e11-f31b-4433-8f87-5b97934db7ac
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Kilburn, J. D.
c02957da-baca-4138-961a-a85170d11dd8
Jullian, V., Shepherd, E., Gelbrich, T., Hursthouse, M. B. and Kilburn, J. D.
(2000)
New macrobicyclic receptors for amino acids.
Tetrahedron Letters, 41 (20), .
(doi:10.1016/S0040-4039(00)00488-3).
Abstract
Two new receptors, 9 and 13, have been prepared, utilising a pyridyl aryl ether unit in the rim of the macrobicyclic structure, and the crystal structures for both of these receptors are reported. The presence of the pyridyl unit provides additional hydrogen bonding functionality in comparison to earlier structures of this type, and 9 is an effective receptor for N-acetyl L-asparagine carboxylate in CH2Cl2.
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More information
Published date: 21 May 2000
Keywords:
host-guest, receptor, amino acid
identification, derivatives, sequence, peptides
Identifiers
Local EPrints ID: 18953
URI: http://eprints.soton.ac.uk/id/eprint/18953
ISSN: 0040-4039
PURE UUID: 07511ce4-6f09-4cb3-8fcf-2ad91dcf8762
Catalogue record
Date deposited: 15 Dec 2005
Last modified: 15 Mar 2024 06:09
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Contributors
Author:
V. Jullian
Author:
E. Shepherd
Author:
T. Gelbrich
Author:
J. D. Kilburn
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