Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
magnetic-properties, crystal-structure, superconductor, ions
2426-2428
Rashid, S.
def6a870-c532-4b51-a2f9-7a7019c72872
Turner, S. S.
5fac7326-12c8-49e0-b494-24834da76f5e
Day, P.
369f0667-c086-47c2-b22c-7b07afd64354
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
29 May 2000
Rashid, S.
def6a870-c532-4b51-a2f9-7a7019c72872
Turner, S. S.
5fac7326-12c8-49e0-b494-24834da76f5e
Day, P.
369f0667-c086-47c2-b22c-7b07afd64354
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B.
(2000)
Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-).
Inorganic Chemistry, 39 (11), .
(doi:10.1021/ic991409w).
Abstract
The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
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Published date: 29 May 2000
Keywords:
magnetic-properties, crystal-structure, superconductor, ions
Identifiers
Local EPrints ID: 18963
URI: http://eprints.soton.ac.uk/id/eprint/18963
ISSN: 0020-1669
PURE UUID: d25a6528-7062-4574-b183-0e394ff2e014
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Date deposited: 17 Jan 2006
Last modified: 15 Mar 2024 06:09
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Author:
S. Rashid
Author:
S. S. Turner
Author:
P. Day
Author:
M. E. Light
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