The University of Southampton
University of Southampton Institutional Repository

Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)

Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
magnetic-properties, crystal-structure, superconductor, ions
0020-1669
2426-2428
Rashid, S.
def6a870-c532-4b51-a2f9-7a7019c72872
Turner, S. S.
5fac7326-12c8-49e0-b494-24834da76f5e
Day, P.
369f0667-c086-47c2-b22c-7b07afd64354
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Hursthouse, M. B.
276e7125-0773-43f6-97e3-77106e9b6e8f
Rashid, S.
def6a870-c532-4b51-a2f9-7a7019c72872
Turner, S. S.
5fac7326-12c8-49e0-b494-24834da76f5e
Day, P.
369f0667-c086-47c2-b22c-7b07afd64354
Light, M. E.
5f2f6119-008d-4681-8ea0-e32559c94ddd
Hursthouse, M. B.
276e7125-0773-43f6-97e3-77106e9b6e8f

Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B. (2000) Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-). Inorganic Chemistry, 39 (11), 2426-2428. (doi:10.1021/ic991409w).

Record type: Article

Abstract

The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.

Full text not available from this repository.

More information

Published date: 29 May 2000
Keywords: magnetic-properties, crystal-structure, superconductor, ions

Identifiers

Local EPrints ID: 18963
URI: http://eprints.soton.ac.uk/id/eprint/18963
ISSN: 0020-1669
PURE UUID: d25a6528-7062-4574-b183-0e394ff2e014

Catalogue record

Date deposited: 17 Jan 2006
Last modified: 15 Jul 2019 19:28

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×