Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B.
Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
Inorganic Chemistry, 39, (11), . (doi:10.1021/ic991409w).
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The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
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