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Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)

Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B. (2000) Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-) Inorganic Chemistry, 39, (11), pp. 2426-2428. (doi:10.1021/ic991409w).

Record type: Article

Abstract

The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.

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More information

Published date: 29 May 2000
Keywords: magnetic-properties, crystal-structure, superconductor, ions

Identifiers

Local EPrints ID: 18963
URI: http://eprints.soton.ac.uk/id/eprint/18963
ISSN: 0020-1669
PURE UUID: d25a6528-7062-4574-b183-0e394ff2e014

Catalogue record

Date deposited: 17 Jan 2006
Last modified: 17 Jul 2017 16:34

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Contributors

Author: S. Rashid
Author: S. S. Turner
Author: P. Day
Author: M. E. Light
Author: M. B. Hursthouse

University divisions

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