Muncaster, G., Sankar, G., Catlow, C. R. A., Thomas, J. M., Coles, S. J. and Hursthouse, M.
The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O
Chemistry of Materials, 12, (1), . (doi:10.1021/cm990500v).
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Crystal structure of (K5CoW12O40)-W-III. 20H(2)O is obtained from a detailed single-crystal study. The interatomic distance, in particular the Co(III)-O distance obtained from the present study is in close agreement with the Co K-edge EXAFS data of the title compound. This material will serve as a good model system for understanding the redox properties of microporous cobalt-substituted aluminophosphate catalysts, since the title compound is noted as a rare example of Co(III) in tetrahedral coordination.
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