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The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O

Muncaster, G., Sankar, G., Catlow, C. R. A., Thomas, J. M., Coles, S. J. and Hursthouse, M. (2000) The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O Chemistry of Materials, 12, (1), pp. 16-18. (doi:10.1021/cm990500v).

Record type: Article

Abstract

Crystal structure of (K5CoW12O40)-W-III. 20H(2)O is obtained from a detailed single-crystal study. The interatomic distance, in particular the Co(III)-O distance obtained from the present study is in close agreement with the Co K-edge EXAFS data of the title compound. This material will serve as a good model system for understanding the redox properties of microporous cobalt-substituted aluminophosphate catalysts, since the title compound is noted as a rare example of Co(III) in tetrahedral coordination.

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More information

Published date: 1 January 2000
Keywords: molecular-sieve, redox centers, catalysts, cyclohexane, chemistry, lewis

Identifiers

Local EPrints ID: 18981
URI: http://eprints.soton.ac.uk/id/eprint/18981
ISSN: 0897-4756
PURE UUID: 93d26ecc-d431-46e1-99d4-3f3883366339

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Date deposited: 18 Jan 2006
Last modified: 17 Jul 2017 16:34

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Contributors

Author: G. Muncaster
Author: G. Sankar
Author: C. R. A. Catlow
Author: J. M. Thomas
Author: S. J. Coles
Author: M. Hursthouse

University divisions

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